|
|
oleoyl-[acyl-carrier_protein] + H2O <=> [acyl-carrier_protein] + oleic_acid + H+
|
3.1.2.14
oleoyl-[acyl-carrier-protein] hydrolase
3.1.2.2
palmitoyl-CoA hydrolase
3.1.2.20
acyl-CoA hydrolase
3.1.2.21
dodecanoyl-[acyl-carrier-protein] hydrolase
|
–
–
–
–
|
BMK
|
|
BRENDA:
BR10674
KEGG:
R02814
MetaCyc:
3.1.2.14-RXN
|
|
|
|
dodecanoyl-[acyl-carrier_protein] + H2O <=> [acyl-carrier_protein] + laurate + H+
|
3.1.2.14
oleoyl-[acyl-carrier-protein] hydrolase
3.1.2.21
dodecanoyl-[acyl-carrier-protein] hydrolase
|
–
–
|
BMK
|
|
BRENDA:
BR2506;
BS12699
KEGG:
R04014
MetaCyc:
3.1.2.21-RXN
SABIO-RK:
3749
|
|
|
|
sn-3-D-galactosyl-sn-2-acylglycerol + acyl-[acyl-carrier_protein] <=> [acyl-carrier_protein] + monogalactosyldiacylglycerol
|
2.3.1.141
galactosylacylglycerol O-acyltransferase
|
–
|
K
|
|
BRENDA:
BR44002
KEGG:
R04473
MetaCyc:
2.3.1.141-RXN
|
|
|
|
acetyl-CoA + [acyl-carrier_protein] <=> CoA + acetyl-[acyl-carrier_protein]
|
2.3.1
2.3.1.180
beta-ketoacyl-[acyl-carrier-protein] synthase III
2.3.1.38
[acyl-carrier-protein] S-acetyltransferase
2.3.1.39
[acyl-carrier-protein] S-malonyltransferase
2.3.1.85
fatty-acid synthase system
2.3.1.86
fatty-acyl-CoA synthase system
2.7.8.7
holo-[acyl-carrier-protein] synthase
|
–
–
–
–
–
–
–
|
BMK
|
|
BRENDA:
BR44038;
BS455168;
BS455169
KEGG:
R01624
MetaCyc:
ACP-S-ACETYLTRANSFER-RXN
SABIO-RK:
1766
|
|
|
|
malonyl-CoA + [acyl-carrier_protein] <=> CoA + malonyl-[acyl-carrier_protein]
|
2.3.1
2.3.1.39
[acyl-carrier-protein] S-malonyltransferase
2.3.1.85
fatty-acid synthase system
2.3.1.86
fatty-acyl-CoA synthase system
|
–
–
–
–
|
BMK
|
|
BRENDA:
BR44039
KEGG:
R01626
MetaCyc:
MALONYL-COA-ACP-TRANSACYL-RXN
SABIO-RK:
1767
|
|
|
|
acyl-[acyl-carrier_protein] + 2-acylglycerophosphoethanolamine <=> [acyl-carrier_protein] + phosphatidylethanolamine
|
2.3.1.40
acyl-[acyl-carrier-protein]---phospholipid O-acyltransferase
|
–
|
K
|
|
BRENDA:
BR44041
KEGG:
R04864
MetaCyc:
ACYLGPEACYLTRANS-RXN
|
|
|
|
pimeloyl-[acyl-carrier_protein] + L-alanine + H+ <=> (8S)-8-amino-7-oxononanoate + CO2 + [acyl-carrier_protein]
|
2.3.1.47
8-amino-7-oxononanoate synthase
|
–
|
BMK
|
|
BRENDA:
BR44048
KEGG:
R10124
MetaCyc:
RXN-11484
|
|
|
|
S-adenosyl-L-methionine + acyl-[acyl-carrier_protein] <=> [acyl-carrier_protein] + S-methyl-5''-thioadenosine + an_N-acyl-L-homoserine_lactone + H+
|
2.3.1.184
acyl-homoserine-lactone synthase
|
–
|
MK
|
|
BRENDA:
BR48844
KEGG:
R08940
MetaCyc:
2.3.1.184-RXN
|
|
|
|
(3R)-3-hydroxymyristoyl-[acyl-carrier_protein] + UDP-3-O-((3R)-3-hydroxymyristoyl)-alpha-D-glucosamine <=> UDP-2,3-bis((3R)-3-hydroxymyristoyl)-alpha-D-glucosamine + [acyl-carrier_protein] + H+
|
2.3.1.191
UDP-3-O-(3-hydroxymyristoyl)glucosamine N-acyltransferase
|
–
|
BMK
|
|
BRENDA:
BR49174
KEGG:
R04550
MetaCyc:
UDPHYDROXYMYRGLUCOSAMNACETYLTRANS-RXN
|
|
|
|
hexanoyl-[acyl-carrier_protein] + malonyl-CoA + H+ <=> norsolorinic_acid_anthrone + [acyl-carrier_protein] + CoA + CO2 + H2O
|
2.3.1.221
noranthrone synthase
|
–
|
MK
|
|
BRENDA:
BR50415
KEGG:
R10239
MetaCyc:
RXN-9479
|
|
|
|
hexanoate + [acyl-carrier_protein] + ATP <=> hexanoyl-[acyl-carrier_protein] + AMP + diphosphate
|
6.2.1.20
long-chain-fatty-acid---[acyl-carrier-protein] ligase
6.2.1.47
medium-chain-fatty-acid---[acyl-carrier-protein] ligase
|
–
–
|
M
|
|
BRENDA:
BR51785
KEGG:
R12148
MetaCyc:
RXN-16468
|
|
|
|
L-ornithine + (3R)-3-hydroxyacyl-[acyl-carrier_protein] <=> a_lyso-ornithine_lipid + [acyl-carrier_protein] + H+
|
2.3.2.30
L-ornithine Nalpha-acyltransferase
|
–
|
M
|
|
BRENDA:
BR52166
KEGG:
R11801
MetaCyc:
RXN-12431
|
|
|
|
a_lyso-ornithine_lipid + acyl-[acyl-carrier_protein] <=> an_ornithine_lipid + [acyl-carrier_protein]
|
2.3.1.270
lyso-ornithine lipid O-acyltransferase
|
–
|
M
|
|
BRENDA:
BR52410
KEGG:
R12086
MetaCyc:
RXN-12432
|
|
|
|
acyl-[acyl-carrier_protein] + phosphate <=> acyl_phosphate + [acyl-carrier_protein]
|
2.3.1.274
phosphate acyltransferase
|
–
|
MK
|
|
BRENDA:
BR52533
KEGG:
R12240
MetaCyc:
RXN-9590
|
|
|
|
fatty_acid + [acyl-carrier_protein] + ATP <=> palmitoyl-[acyl-carrier_protein] + AMP + diphosphate
|
6.2.1.20
long-chain-fatty-acid---[acyl-carrier-protein] ligase
|
–
|
MK
|
|
BRENDA:
BR72;
BS211;
BS214
KEGG:
R01406
MetaCyc:
ACYLACPSYNTH-RXN;
RXN-13267;
RXN-13268
|
|
|
|
tetradecanoyl-[acyl-carrier_protein] + H2O <=> [acyl-carrier_protein] + myristic_acid + H+
|
3.1.2.14
oleoyl-[acyl-carrier-protein] hydrolase
3.1.2.21
dodecanoyl-[acyl-carrier-protein] hydrolase
|
–
–
|
MK
|
|
BRENDA:
BS12700
KEGG:
R08159
MetaCyc:
RXN-10727
SABIO-RK:
15487
|
|
|
|
palmitoyl-[acyl-carrier_protein] + H2O <=> fatty_acid + [acyl-carrier_protein] + H+
|
2.3.1.85
fatty-acid synthase system
3.1.2.14
oleoyl-[acyl-carrier-protein] hydrolase
3.1.2.21
dodecanoyl-[acyl-carrier-protein] hydrolase
|
–
–
–
|
BMK
|
|
BRENDA:
BS12701;
BS364432;
BS382837;
BS432386
KEGG:
R01706;
R08163;
R12329
MetaCyc:
RXN-17108;
RXN-7902;
RXN-9548;
RXN-9549
|
|
|
|
laurate + [acyl-carrier_protein] + ATP <=> dodecanoyl-[acyl-carrier_protein] + AMP + diphosphate
|
6.2.1.20
long-chain-fatty-acid---[acyl-carrier-protein] ligase
6.2.1.47
medium-chain-fatty-acid---[acyl-carrier-protein] ligase
|
–
–
|
|
|
BRENDA:
BS213
MetaCyc:
RXN-13264
|
|
|
|
Octanoate + [acyl-carrier_protein] + ATP <=> octanoyl-[acyl-carrier_protein] + AMP + diphosphate
|
6.2.1.20
long-chain-fatty-acid---[acyl-carrier-protein] ligase
6.2.1.47
medium-chain-fatty-acid---[acyl-carrier-protein] ligase
|
–
–
|
B
|
|
BRENDA:
BS215
MetaCyc:
RXN-5741
|
|
|
|
Decanoate + [acyl-carrier_protein] + ATP <=> decanoyl-[acyl-carrier_protein] + AMP + diphosphate
|
6.2.1.20
long-chain-fatty-acid---[acyl-carrier-protein] ligase
6.2.1.47
medium-chain-fatty-acid---[acyl-carrier-protein] ligase
|
–
–
|
M
|
|
BRENDA:
BS216
MetaCyc:
RXN-21395
|
|
|
|
myristic_acid + [acyl-carrier_protein] + ATP <=> tetradecanoyl-[acyl-carrier_protein] + AMP + diphosphate
|
6.2.1.20
long-chain-fatty-acid---[acyl-carrier-protein] ligase
|
–
|
|
|
BRENDA:
BS217
MetaCyc:
RXN-13266
|
|
|
|
acyl-[acyl-carrier_protein] + sn-glycerol_3-phosphate <=> lysophosphatidic_acid + [acyl-carrier_protein]
|
2.3.1.15
glycerol-3-phosphate 1-O-acyltransferase
|
–
|
M
|
|
BRENDA:
BS320527
KEGG:
R09380
MetaCyc:
RXN-10462
|
|
|
|
sn-glycerol_3-phosphate + stearoyl-[acyl-carrier_protein] <=> 1-stearoyl-sn-glycerol_3-phosphate + [acyl-carrier_protein]
|
2.3.1.15
glycerol-3-phosphate 1-O-acyltransferase
|
–
|
M
|
|
BRENDA:
BS320529
MetaCyc:
RXN-16024
|
|
|
|
palmitoyl-[acyl-carrier_protein] + sn-glycerol_3-phosphate <=> 1-palmitoyl-sn-glycerol_3-phosphate + [acyl-carrier_protein]
|
2.3.1.15
glycerol-3-phosphate 1-O-acyltransferase
|
–
|
|
|
BRENDA:
BS320530
MetaCyc:
RXN-17018
SABIO-RK:
11371
|
|
|
|
cis-vaccenoyl-[acyl-carrier_protein] + sn-glycerol_3-phosphate <=> 1-cis-vaccenoyl-sn-glycerol_3-phosphate + [acyl-carrier_protein]
|
2.3.1.15
glycerol-3-phosphate 1-O-acyltransferase
|
–
|
|
|
BRENDA:
BS320531
MetaCyc:
RXN-17016
|
|
|
|
CoA + octanoyl-[acyl-carrier_protein] <=> [acyl-carrier_protein] + octanoyl-CoA
|
2.3.1
2.3.1.38
[acyl-carrier-protein] S-acetyltransferase
2.3.1.85
fatty-acid synthase system
2.8.3
|
–
–
–
–
|
MK
|
|
BRENDA:
BS320850;
BS456116
KEGG:
R12430
MetaCyc:
RXN-14954
|
|
|
|
butyryl-[acyl-carrier_protein] + malonyl-[acyl-carrier_protein] + H+ <=> 3-oxohexanoyl-[acyl-carrier_protein] + CO2 + [acyl-carrier_protein]
|
2.3.1
2.3.1.179
beta-ketoacyl-[acyl-carrier-protein] synthase II
2.3.1.41
beta-ketoacyl-[acyl-carrier-protein] synthase I
2.3.1.85
fatty-acid synthase system
2.3.1.86
fatty-acyl-CoA synthase system
|
–
–
–
–
–
|
BMK
|
|
BRENDA:
BS320867
KEGG:
R04952
MetaCyc:
RXN-9516
SABIO-RK:
4590
|
|
|
|
hexanoyl-[acyl-carrier_protein] + malonyl-[acyl-carrier_protein] + H+ <=> 3-oxooctanoyl-[acyl-carrier_protein] + CO2 + [acyl-carrier_protein]
|
2.3.1
2.3.1.179
beta-ketoacyl-[acyl-carrier-protein] synthase II
2.3.1.41
beta-ketoacyl-[acyl-carrier-protein] synthase I
2.3.1.85
fatty-acid synthase system
2.3.1.86
fatty-acyl-CoA synthase system
|
–
–
–
–
–
|
BMK
|
|
BRENDA:
BS320869
KEGG:
R04957
MetaCyc:
RXN-9523
SABIO-RK:
4595
|
|
|
|
octanoyl-[acyl-carrier_protein] + malonyl-[acyl-carrier_protein] + H+ <=> 3-oxodecanoyl-[acyl-carrier_protein] + CO2 + [acyl-carrier_protein]
|
2.3.1
2.3.1.179
beta-ketoacyl-[acyl-carrier-protein] synthase II
2.3.1.41
beta-ketoacyl-[acyl-carrier-protein] synthase I
2.3.1.85
fatty-acid synthase system
2.3.1.86
fatty-acyl-CoA synthase system
|
–
–
–
–
–
|
BMK
|
|
BRENDA:
BS320870
KEGG:
R04960
MetaCyc:
RXN-9527
SABIO-RK:
4598
|
|
|
|
dodecanoyl-[acyl-carrier_protein] + malonyl-[acyl-carrier_protein] + H+ <=> 3-oxotetradecanoyl-[acyl-carrier_protein] + CO2 + [acyl-carrier_protein]
|
2.3.1
2.3.1.179
beta-ketoacyl-[acyl-carrier-protein] synthase II
2.3.1.41
beta-ketoacyl-[acyl-carrier-protein] synthase I
2.3.1.85
fatty-acid synthase system
2.3.1.86
fatty-acyl-CoA synthase system
|
–
–
–
–
–
|
BMK
|
|
BRENDA:
BS320872
KEGG:
R04726
MetaCyc:
RXN-9535
SABIO-RK:
4382
|
|
|
|
tetradecanoyl-[acyl-carrier_protein] + malonyl-[acyl-carrier_protein] + H+ <=> 3-oxohexadecanoyl-[acyl-carrier_protein] + CO2 + [acyl-carrier_protein]
|
2.3.1
2.3.1.179
beta-ketoacyl-[acyl-carrier-protein] synthase II
2.3.1.41
beta-ketoacyl-[acyl-carrier-protein] synthase I
2.3.1.85
fatty-acid synthase system
2.3.1.86
fatty-acyl-CoA synthase system
|
–
–
–
–
–
|
BMK
|
|
BRENDA:
BS320873
KEGG:
R04968
MetaCyc:
RXN-9539
SABIO-RK:
4606
|
|
|
|
palmitoyl-[acyl-carrier_protein] + malonyl-[acyl-carrier_protein] + H+ <=> 3-oxooctadecanoyl-[acyl-carrier_protein] + CO2 + [acyl-carrier_protein]
|
2.3.1
2.3.1.179
beta-ketoacyl-[acyl-carrier-protein] synthase II
2.3.1.199
very-long-chain 3-oxoacyl-CoA synthase
2.3.1.41
beta-ketoacyl-[acyl-carrier-protein] synthase I
|
–
–
–
–
|
MK
|
|
BRENDA:
BS320874;
BS377477
KEGG:
R07762
MetaCyc:
RXN-9632
SABIO-RK:
11307
|
|
|
|
palmitoleoyl-[acyl-carrier_protein] + malonyl-[acyl-carrier_protein] + H+ <=> cis-vaccenoyl-[acyl-carrier_protein] + CO2 + [acyl-carrier_protein]
|
2.3.1.179
beta-ketoacyl-[acyl-carrier-protein] synthase II
2.3.1.41
beta-ketoacyl-[acyl-carrier-protein] synthase I
|
–
–
|
BM
|
|
BRENDA:
BS320877
MetaCyc:
2.3.1.179-RXN
|
|
|
|
acyl-[acyl-carrier_protein] + lysophosphatidic_acid <=> phosphatidic_acid + [acyl-carrier_protein]
|
2.3.1.51
1-acylglycerol-3-phosphate O-acyltransferase
|
–
|
M
|
|
BRENDA:
BS321039
KEGG:
R09381
MetaCyc:
1-ACYLGLYCEROL-3-P-ACYLTRANSFER-RXN
|
|
|
|
2''-(5''''-triphospho-alpha-D-ribosyl)-3''-dephospho-CoA + apo_[citrate-lyase_acyl-carrier_protein] <=> [acyl-carrier_protein] + diphosphate
|
2.7.7.61
citrate lyase holo-[acyl-carrier protein] synthase
|
–
|
M
|
|
BRENDA:
BS323485
MetaCyc:
2.7.7.61-RXN
|
|
|
|
acetyl-[acyl-carrier_protein] + H2O <=> [acyl-carrier_protein] + acetate + H+
|
3.1.2.16
citrate-lyase deacetylase
|
–
|
M
|
|
BRENDA:
BS358864
MetaCyc:
CITRATE-PRO-3S-LYASE-THIOLESTERASE-RXN
|
|
|
|
palmitoleoyl-[acyl-carrier_protein] + H2O <=> palmitoleic_acid + [acyl-carrier_protein] + H+
|
3.1.2.14
oleoyl-[acyl-carrier-protein] hydrolase
|
–
|
MK
|
|
BRENDA:
BS364433
KEGG:
R08162
MetaCyc:
RXN-9550
|
|
|
|
acetyl-[acyl-carrier_protein] + malonyl-[acyl-carrier_protein] + H+ <=> [acyl-carrier_protein] + acetoacetyl-[acyl-carrier_protein] + CO2
|
2.3.1
2.3.1.179
beta-ketoacyl-[acyl-carrier-protein] synthase II
2.3.1.41
beta-ketoacyl-[acyl-carrier-protein] synthase I
2.3.1.85
fatty-acid synthase system
2.3.1.86
fatty-acyl-CoA synthase system
|
–
–
–
–
–
|
MK
|
|
BRENDA:
BS376191
KEGG:
R04355
MetaCyc:
3-OXOACYL-ACP-SYNTH-BASE-RXN
SABIO-RK:
4051
|
|
|
|
S-adenosyl-L-methionine + 3-oxododecanoyl-[acyl-carrier_protein] <=> [acyl-carrier_protein] + S-methyl-5''-thioadenosine + N-(3-oxododecanoyl)-L-homoserine_lactone + H+
|
2.3.1.184
acyl-homoserine-lactone synthase
|
–
|
|
|
BRENDA:
BS380746
MetaCyc:
RXN-10023
|
|
|
|
S-adenosyl-L-methionine + 3-oxohexanoyl-[acyl-carrier_protein] <=> [acyl-carrier_protein] + S-methyl-5''-thioadenosine + N-(3-oxohexanoyl)-L-homoserine_lactone + H+
|
2.3.1.184
acyl-homoserine-lactone synthase
|
–
|
|
|
BRENDA:
BS380747
MetaCyc:
RXN-10022
|
|
|
|
S-adenosyl-L-methionine + 3-oxooctanoyl-[acyl-carrier_protein] <=> [acyl-carrier_protein] + S-methyl-5''-thioadenosine + N-(3-oxooctanoyl)-L-homoserine_lactone + H+
|
2.3.1.184
acyl-homoserine-lactone synthase
|
–
|
|
|
BRENDA:
BS380748
MetaCyc:
RXN-10020
|
|
|
|
S-adenosyl-L-methionine + butyryl-[acyl-carrier_protein] <=> [acyl-carrier_protein] + S-methyl-5''-thioadenosine + PAI-1-2 + H+
|
2.3.1.184
acyl-homoserine-lactone synthase
|
–
|
|
|
BRENDA:
BS380749
KEGG:
R08939
MetaCyc:
RXN-10024
SABIO-RK:
7009
|
|
|
|
S-adenosyl-L-methionine + octanoyl-[acyl-carrier_protein] <=> [acyl-carrier_protein] + S-methyl-5''-thioadenosine + VAI-1-2 + H+
|
2.3.1.184
acyl-homoserine-lactone synthase
|
–
|
|
|
BRENDA:
BS380752
MetaCyc:
RXN-10025
|
|
|
|
UDP-N-acetyl-D-glucosamine + (3R)-3-hydroxydecanoyl-[acyl-carrier_protein] <=> UDP-3-O-hydroxydecanoyl-N-acetylglucosamine + [acyl-carrier_protein]
|
2.3.1.129
acyl-[acyl-carrier-protein]---UDP-N-acetylglucosamine O-acyltransferase
|
–
|
M
|
|
BRENDA:
BS398236
MetaCyc:
RXN-20789
|
|
|
|
hexadecanal + [acyl-carrier_protein] + NADP+ <=> palmitoyl-[acyl-carrier_protein] + NADPH + H+
|
1.2.1.50
long-chain acyl-protein thioester reductase
1.2.1.80
long-chain acyl-[acyl-carrier-protein] reductase
|
–
–
|
M
|
|
BRENDA:
BS426898
MetaCyc:
RXN-11706
|
|
|
|
palmitoleoyl-[acyl-carrier_protein] + alpha-Kdo-(2->4)-alpha-Kdo-(2->6)-lipid_IVA <=> alpha-Kdo-(2->4)-alpha-Kdo-(2->6)-(palmitoleoyl)-lipid_IVA + [acyl-carrier_protein]
|
2.3.1.242
Kdo2-lipid IVA palmitoleoyltransferase
|
–
|
BMK
|
|
BRENDA:
BS427337
KEGG:
R10906
MetaCyc:
PALMITOTRANS-RXN
|
|
|
|
octadecanal + NADP+ + [acyl-carrier_protein] <=> stearoyl-[acyl-carrier_protein] + NADPH + H+
|
1.2.1.80
long-chain acyl-[acyl-carrier-protein] reductase
|
–
|
M
|
|
BRENDA:
BS439913
MetaCyc:
RXN-11707
|
|
|
|
octadecanal + NAD+ + [acyl-carrier_protein] <=> stearoyl-[acyl-carrier_protein] + NADH + H+
|
1.2.1.80
long-chain acyl-[acyl-carrier-protein] reductase
|
–
|
|
|
BRENDA:
BS439913-a
MetaCyc:
RXN-11707_WOP
|
|
|
|
palmitoyl-[acyl-carrier_protein] + CoA <=> palmitoyl-CoA + [acyl-carrier_protein]
|
2.3.1
2.3.1.85
fatty-acid synthase system
2.3.1.86
fatty-acyl-CoA synthase system
|
–
–
–
|
MK
|
|
BRENDA:
BS456174
KEGG:
R10700
MetaCyc:
RXN3O-9780
|
|
|
|
[acyl-carrier_protein] + H2O <=> 4''-phosphopantetheine + apo-acyl-carrier_protein
|
3.1.4.14
[acyl-carrier-protein] phosphodiesterase
|
–
|
BK
|
|
BRENDA:
BR15954
KEGG:
R01623
|
|
|
|
acyl-[acyl-carrier_protein] + malonyl-[acyl-carrier_protein] <=> 3-oxoacyl-[acyl-carrier_protein] + CO2 + [acyl-carrier_protein]
|
2.3.1.179
beta-ketoacyl-[acyl-carrier-protein] synthase II
2.3.1.293
meromycolic acid 3-oxoacyl-(acyl carrier protein) synthase I
2.3.1.41
beta-ketoacyl-[acyl-carrier-protein] synthase I
|
–
–
–
|
K
|
|
BRENDA:
BR44042
KEGG:
R02768
|
|
|
|
CoA-[4''-phosphopantetheine] + apo-acyl-carrier_protein <=> adenosine_3'',5''-bisphosphate + [acyl-carrier_protein]
|
2.7.8
2.7.8.7
holo-[acyl-carrier-protein] synthase
|
–
–
|
BK
|
|
BRENDA:
BR48095
KEGG:
R01625
SABIO-RK:
335
|
|
|
|
ATP + acetate + [acyl-carrier_protein] <=> AMP + diphosphate + acetyl-[acyl-carrier_protein]
|
6.2.1.35
acetate---[acyl-carrier protein] ligase
|
–
|
|
|
BRENDA:
BR48976
KEGG:
R09475
|
|
|
|
hexadecanal + [acyl-carrier_protein] + NADP+ <=> stearoyl-[acyl-carrier_protein] + NADPH + H+
|
1.2.1.80
long-chain acyl-[acyl-carrier-protein] reductase
|
–
|
|
|
BRENDA:
BR49399
KEGG:
R09485
|
|
|
|
hexadecanal + [acyl-carrier_protein] + NAD+ <=> stearoyl-[acyl-carrier_protein] + NADH + H+
|
1.2.1.80
long-chain acyl-[acyl-carrier-protein] reductase
|
–
|
|
|
BRENDA:
BR49399-a
KEGG:
R09484
|
|
|
|
a_medium-chain_3-oxoacyl-[acyl-carrier_protein] + dihydroxyacetone_phosphate <=> 2-oxo-3-(phosphooxy)propyl_3-oxoalkanoate + [acyl-carrier_protein]
|
2.3.1.277
2-oxo-3-(phosphooxy)propyl 3-oxoalkanoate synthase
|
–
|
|
|
BRENDA:
BR52575
KEGG:
R12289
|
|
|
|
[acyl-carrier_protein] + acetate + ATP <=> acetyl-[acyl-carrier_protein] + diphosphate + AMP
|
6.2.1.22
[citrate (pro-3S)-lyase] ligase
|
–
|
M
|
|
BRENDA:
BR74;
BS368967
KEGG:
R04449
MetaCyc:
CITC-RXN
SABIO-RK:
4134
|
|
|
|
ATP + a_carboxylate + [acyl-carrier_protein] <=> AMP + diphosphate + acyl-[acyl-carrier_protein]
|
6.2.1
6.2.1.20
long-chain-fatty-acid---[acyl-carrier-protein] ligase
|
–
–
|
|
|
BRENDA:
BS209
KEGG:
R07325
|
|
|
|
decanoyl-[acyl-carrier_protein] + H2O <=> [acyl-carrier_protein] + Decanoate
|
3.1.2.14
oleoyl-[acyl-carrier-protein] hydrolase
3.1.2.21
dodecanoyl-[acyl-carrier-protein] hydrolase
|
–
–
|
K
|
|
BRENDA:
BS446229
KEGG:
R08158
|
|
|
|
octanoyl-[acyl-carrier_protein] + H2O <=> [acyl-carrier_protein] + Octanoate
|
3.1.2.14
oleoyl-[acyl-carrier-protein] hydrolase
3.1.2.21
dodecanoyl-[acyl-carrier-protein] hydrolase
|
–
–
|
K
|
|
BRENDA:
BS446327
KEGG:
R08157
|
|
|
|
tetradecanoyl-[acyl-carrier_protein] + dodecanoyl-Kdo2-lipid_IVA <=> Kdo2-lipid_A + [acyl-carrier_protein]
|
2.3.1.243
lauroyl-Kdo2-lipid IVA myristoyltransferase
|
–
|
MK
|
|
BRENDA:
BS454219
KEGG:
R05075
MetaCyc:
MYRISTOYLACYLTRAN-RXN
|
|
|
|
dodecanoyl-[acyl-carrier_protein] + alpha-Kdo-(2->4)-alpha-Kdo-(2->6)-lipid_IVA <=> dodecanoyl-Kdo2-lipid_IVA + [acyl-carrier_protein]
|
2.3.1.241
Kdo2-lipid IVA lauroyltransferase
|
–
|
MK
|
|
BRENDA:
BS455136
KEGG:
R05146
MetaCyc:
LAUROYLACYLTRAN-RXN
|
|
|
|
tetradecanoyl-[acyl-carrier_protein] + alpha-Kdo-(2->4)-alpha-Kdo-(2->6)-(palmitoleoyl)-lipid_IVA <=> Palmitoleoyl-myristoyl-KDO2-lipid_A + [acyl-carrier_protein]
|
2.3.1.243
lauroyl-Kdo2-lipid IVA myristoyltransferase
|
–
|
MK
|
|
KEGG:
R12197
MetaCyc:
MYRPALMTRAN-RXN
|
|
|
|
malonyl-[acyl-carrier_protein]_methyl_ester + malonyl-[acyl-carrier_protein] + H+ <=> 3-Ketoglutaryl-[acp]_methyl_ester + CO2 + [acyl-carrier_protein]
|
2.3.1.179
beta-ketoacyl-[acyl-carrier-protein] synthase II
2.3.1.41
beta-ketoacyl-[acyl-carrier-protein] synthase I
|
–
–
|
MK
|
|
KEGG:
R10115
MetaCyc:
RXN-11474
|
|
|
|
Glutaryl-[acp]_methyl_ester + malonyl-[acyl-carrier_protein] + H+ <=> 3-Ketopimeloyl-[acp]_methyl_ester + CO2 + [acyl-carrier_protein]
|
2.3.1.179
beta-ketoacyl-[acyl-carrier-protein] synthase II
2.3.1.41
beta-ketoacyl-[acyl-carrier-protein] synthase I
|
–
–
|
MK
|
|
KEGG:
R10119
MetaCyc:
RXN-11479
|
|
|
|
decanoyl-[acyl-carrier_protein] + malonyl-[acyl-carrier_protein] + H+ <=> 3-oxododecanoyl-[acyl-carrier_protein] + CO2 + [acyl-carrier_protein]
|
2.3.1
2.3.1.179
beta-ketoacyl-[acyl-carrier-protein] synthase II
2.3.1.41
beta-ketoacyl-[acyl-carrier-protein] synthase I
2.3.1.85
fatty-acid synthase system
2.3.1.86
fatty-acyl-CoA synthase system
|
–
–
–
–
–
|
MK
|
|
KEGG:
R04963
MetaCyc:
RXN-9531
SABIO-RK:
4601
|
|
|
|
UDP-N-acetyl-D-glucosamine + (3R)-3-hydroxymyristoyl-[acyl-carrier_protein] <=> UDP-3-O-((R)-3-hydroxymyristoyl)-N-acetylglucosamine + [acyl-carrier_protein]
|
2.3.1.129
acyl-[acyl-carrier-protein]---UDP-N-acetylglucosamine O-acyltransferase
|
–
|
MK
|
|
KEGG:
R04567
MetaCyc:
UDPNACETYLGLUCOSAMACYLTRANS-RXN
|
|
|
|
ATP + glycine + [acyl-carrier_protein] <=> AMP + diphosphate + a_glycyl-[acyl-carrier_protein]
|
6.2.1.B4
|
–
|
|
|
BRENDA:
BR49266
SABIO-RK:
13186
|
|
|
|
methylmalonyl-CoA + [acyl-carrier_protein] <=> CoA + a_methylmalonyl-[acyl-carrier_protein]
|
2.3.1.39
[acyl-carrier-protein] S-malonyltransferase
2.3.1.B32
|
–
–
|
|
|
BRENDA:
BR51683;
BS435627;
BS456004
SABIO-RK:
14636
|
|
|
|
oleoyl-[acyl-carrier_protein] + sn-glycerol_3-phosphate <=> [acyl-carrier_protein] + 1-oleoyl-sn-glycerol_3-phosphate
|
2.3.1.15
glycerol-3-phosphate 1-O-acyltransferase
|
–
|
|
|
BRENDA:
BS320528
SABIO-RK:
11372
|
|
|
|
palmitoyl-[acyl-carrier_protein] + phosphate <=> hexadecanoyl_phosphate + [acyl-carrier_protein]
|
2.3.1.274
phosphate acyltransferase
|
–
|
|
|
BRENDA:
BS445544
SABIO-RK:
12851
|
|
|
|
acyl-CoA + n methylmalonyl-CoA + 2n NADPH + 2n H+ + [acyl-carrier_protein] <=> Multi-methyl-branched_acyl-[acp] + (n+1)_CoA + n CO2 + 2n NADP+ + n H2O
|
2.3.1.111
mycocerosate synthase
2.3.1.252
mycolipanoate synthase
|
–
–
|
|
|
KEGG:
R05189
|
|
|
|
acetyl-CoA + 7 malonyl-CoA + [acyl-carrier_protein] <=> 3,5,7,9,11,13,15-Heptaoxo-hexadecanoyl-[acp] + 7 CO2 + 7 CoA
|
2.3.1
|
–
|
K
|
|
KEGG:
R06635
|
|
|
|
butyryl-CoA + 7 malonyl-CoA + [acyl-carrier_protein] <=> 3,5,7,9,11,13,15-Heptaoxo-octadecanoyl-[acp] + 7 CO2 + 7 CoA
|
2.3.1
|
–
|
K
|
|
KEGG:
R06637
|
|
|
|
Malonamoyl-CoA + 8 malonyl-CoA + [acyl-carrier_protein] <=> 18-Carbamoyl-3,5,7,9,11,13,15,17-octaoxooctadecanoyl-[acp] + 8 CO2 + 9 CoA
|
2.3.1
|
–
|
|
|
KEGG:
R06641
|
|
|
|
10 malonyl-CoA + [acyl-carrier_protein] <=> 3,5,7,9,11,13,15,17,19-Nonaoxo-eicosanoyl-[acp] + 10 CO2 + 10 CoA
|
2.3.1
2.3.1.235
tetracenomycin F2 synthase
|
–
–
|
K
|
|
KEGG:
R06643
|
|
|
|
propionyl-CoA + 9 malonyl-CoA + [acyl-carrier_protein] <=> 3,5,7,9,11,13,15,17,19-nonaoxohenicosanoyl-[acp] + 9 CO2 + 9 CoA
|
2.3.1
|
–
|
K
|
|
KEGG:
R06644
|
|
|
|
butyryl-CoA + 9 malonyl-CoA + [acyl-carrier_protein] <=> 3,5,7,9,11,13,15,17,19-Nonaoxo-docosanoyl-[acp] + 9 CO2 + 9 CoA
|
2.3.1
|
–
|
K
|
|
KEGG:
R06645
|
|
|
|
9 malonyl-CoA + 11 NADPH + 10 H+ + S-adenosyl-L-methionine + [acyl-carrier_protein] <=> Dihydromonacolin_L-[acyl-carrier_protein] + 9 CoA + 9 CO2 + 11 NADP+ + S-adenosyl-L-homocysteine + 6 H2O
|
2.3.1.161
lovastatin nonaketide synthase
|
–
|
K
|
|
KEGG:
R07251
|
|
|
|
octanoyl-[acyl-carrier_protein] + protein <=> protein_N6-(octanoyl)lysine + [acyl-carrier_protein]
|
2.3.1.181
lipoyl(octanoyl) transferase
|
–
|
|
|
KEGG:
R07766
|
|
|
|
Lipoyl-[acp] + protein <=> [dihydrolipoyllysine-residue(2-methylpropanoyl)transferase]-lipoyllysine + [acyl-carrier_protein]
|
2.3.1.181
lipoyl(octanoyl) transferase
|
–
|
|
|
KEGG:
R07769
|
|
|
|
ATP + L-glutamate + [acyl-carrier_protein] <=> ADP + phosphate + gamma-L-Glutamyl-[acp]
|
6.2.1.39
[butirosin acyl-carrier protein]---L-glutamate ligase
|
–
|
K
|
|
KEGG:
R08905
|
|
|
|
4-(gamma-L-Glutamylamino)-(2S)-2-hydroxybutanoyl-[acp] + ribostamycin <=> [acyl-carrier_protein] + gamma-L-glutamyl-butirosin_B
|
2.3.2.19
ribostamycin:4-(gamma-L-glutamylamino)-(S)-2-hydroxybutanoyl-[BtrI acyl-carrier protein] 4-(gamma-L-glutamylamino)-(S)-2-hydroxybutanoate transferase
|
–
|
K
|
|
KEGG:
R08909
|
|
|
|
8 malonyl-CoA + [acyl-carrier_protein] <=> 3,5,7,9,11,13,15-Heptaoxo-hexadecanoyl-[acp] + 8 CO2 + 8 CoA
|
2.3.1
|
–
|
K
|
|
KEGG:
R09258
|
|
|
|
9,14-Decaketide_intermediate_1 <=> tetracenomycin_F2 + [acyl-carrier_protein]
|
not assigned
|
–
|
K
|
|
KEGG:
R09355
|
|
|
|
2''-(5-Triphosphoribosyl)-3''-dephospho-CoA + apo-acyl-carrier_protein <=> [acyl-carrier_protein] + diphosphate
|
2.7.7.61
citrate lyase holo-[acyl-carrier protein] synthase
2.7.7.66
malonate decarboxylase holo-[acyl-carrier protein] synthase
|
–
–
|
|
|
KEGG:
R10706
|
|
|
|
monacolin_J_acid + (S)-2-Methylbutanoyl-[acp] <=> lovastatin_acid + [acyl-carrier_protein]
|
2.3.1.238
monacolin J acid methylbutanoate transferase
|
–
|
K
|
|
KEGG:
R11126
|
|
|
|
Dihydromonacolin_L-[acyl-carrier_protein] + H2O <=> [acyl-carrier_protein] + dihydromonacolin_L_acid
|
3.1.2.31
dihydromonacolin L-[lovastatin nonaketide synthase] thioesterase
|
–
|
K
|
|
KEGG:
R11187
|
|
|
|
acetyl-CoA + 3 malonyl-CoA + [acyl-carrier_protein] <=> Orsellinate-[acp] + 4 CoA + 3 CO2 + H2O
|
2.3.1
|
–
|
K
|
|
KEGG:
R11412
|
|
|
|
4-Deoxy-4-thio-alpha-D-digitoxosyl-calicheamicin_T0 + 5-Iodo-2,3-dimethoxyorsellinate-[acp] <=> Calicheamicin_PsAg + [acyl-carrier_protein]
|
not assigned
|
–
|
K
|
|
KEGG:
R11419
|
|
|
|
8 malonyl-CoA + 7 NADPH + 7 H+ + [acyl-carrier_protein] <=> 3-Hydroxyhexadeca-4,6,8,10,12,14-hexaenoyl-[acp] + 8 CoA + 8 CO2 + 6 H2O + 7 NADP+
|
not assigned
|
–
|
K
|
|
KEGG:
R11435
|
|
|
|
3-Hydroxyhexadeca-4,6,8,10,12,14-hexaenoyl-[acp] <=> 1,3,5,7,9,11,13-Pentadecaheptaene + CO2 + [acyl-carrier_protein]
|
not assigned
|
–
|
K
|
|
KEGG:
R11436
|
|
|
|
2 malonyl-CoA + [acyl-carrier_protein] + 2 NADPH + 2 H+ + S-adenosyl-L-methionine <=> (S)-2-Methylbutanoyl-[acp] + 2 CoA + 2 CO2 + 2 NADP+ + S-adenosyl-L-homocysteine + H2O
|
2.3.1.244
2-methylbutanoate polyketide synthase
|
–
|
K
|
|
KEGG:
R11445
|
|
|
|
arachidoyl-CoA + 4 methylmalonyl-CoA + 8 NADPH + 8 H+ + [acyl-carrier_protein] <=> C32-Mycocerosyl-[acp] + 5 CoA + 4 CO2 + 8 NADP+ + 4 H2O
|
2.3.1.111
mycocerosate synthase
|
–
|
|
|
KEGG:
R11450
|
|
|
|
stearoyl-CoA + 3 methylmalonyl-CoA + 6 NADPH + 6 H+ + [acyl-carrier_protein] <=> C27-Mycolipanoyl-[acp] + 4 CoA + 3 CO2 + 6 NADP+ + 3 H2O
|
2.3.1.252
mycolipanoate synthase
|
–
|
|
|
KEGG:
R11451
|
|
|
|
(1H-pyrrole-2-carbonyl)-[peptidyl-carrier_protein] + [acyl-carrier_protein] <=> Pyrrolyl-2-carboxyl-S-[acyl-carrier_protein] + pC3'p
|
2.3.1
|
–
|
K
|
|
KEGG:
R11665
|
|
|
|
Pyrrolyl-2-carboxyl-S-[acyl-carrier_protein] + malonyl-CoA + L-serine <=> 4-Hydroxy-2,2''-bipyrrole-5-methanol + CoA + [acyl-carrier_protein] + 2 CO2 + H2O
|
not assigned
|
–
|
K
|
|
KEGG:
R11667
|
|
|
|
ATP + 4-hydroxybenzoate + [acyl-carrier_protein] <=> AMP + diphosphate + 4-Hydroxybenzoyl-[acp]
|
6.2.1.50
4-hydroxybenzoate adenylyltransferase FadD22
|
–
|
|
|
KEGG:
R11872
|
|
|
|
4-hydroxybenzoyl_adenylate + [acyl-carrier_protein] <=> AMP + 4-Hydroxybenzoyl-[acp]
|
6.2.1.50
4-hydroxybenzoate adenylyltransferase FadD22
|
–
|
|
|
KEGG:
R11873
|
|
|
|
ATP + 17-(4-hydroxyphenyl)heptadecanoate + [acyl-carrier_protein] <=> AMP + diphosphate + 17-(4-Hydroxyphenyl)heptadecanoyl-[acp]
|
6.2.1.51
4-hydroxyphenylalkanoate adenylyltransferase FadD29
|
–
|
|
|
KEGG:
R11922
|
|
|
|
17-(4-hydroxyphenyl)heptadecanoyl_adenylate + [acyl-carrier_protein] <=> AMP + 17-(4-Hydroxyphenyl)heptadecanoyl-[acp]
|
6.2.1.51
4-hydroxyphenylalkanoate adenylyltransferase FadD29
|
–
|
|
|
KEGG:
R11923
|
|
|
|
ATP + 19-(4-hydroxyphenyl)nonadecanoate + [acyl-carrier_protein] <=> AMP + diphosphate + 19-(4-Hydroxyphenyl)nonadecanoyl-[acp]
|
6.2.1.51
4-hydroxyphenylalkanoate adenylyltransferase FadD29
|
–
|
|
|
KEGG:
R11924
|
|
|
|
19-(4-hydroxyphenyl)nonadecanoyl_adenylate + [acyl-carrier_protein] <=> AMP + 19-(4-Hydroxyphenyl)nonadecanoyl-[acp]
|
6.2.1.51
4-hydroxyphenylalkanoate adenylyltransferase FadD29
|
–
|
|
|
KEGG:
R11925
|
|
|
|
palmitoyl-[acyl-carrier_protein] + H._pylori_KDO2-lipid_IVA <=> Stearoyl-KDO2-lipid_IVA + [acyl-carrier_protein]
|
2.3.1
|
–
|
K
|
|
KEGG:
R12193
|
|
|
|
tetradecanoyl-[acyl-carrier_protein] + Stearoyl-KDO2-lipid_IVA <=> H._pylori_KDO2-lipid_A + [acyl-carrier_protein]
|
2.3.1
|
–
|
K
|
|
KEGG:
R12194
|
|
|
|
octanoyl-[acyl-carrier_protein] + Lipoyl-carrier_protein_E2 <=> [Lipoyl-carrier_protein_E2]-N6-octanoyl-L-lysine + [acyl-carrier_protein]
|
2.3.1.181
lipoyl(octanoyl) transferase
|
–
|
K
|
|
KEGG:
R12427
|
|
|
|
octanoyl-[acyl-carrier_protein] + glycine_cleavage_system_H <=> [glycine_cleavage_system_H]-N6-octanoyl-L-lysine + [acyl-carrier_protein]
|
2.3.1.181
lipoyl(octanoyl) transferase
|
–
|
K
|
|
KEGG:
R12428
|
|
|
|
palmitoyl-[acyl-carrier_protein] + malonyl-[acyl-carrier_protein] + H+ <=> long-chain_3-oxoacyl-[acp] + CO2 + [acyl-carrier_protein]
|
2.3.1.41
beta-ketoacyl-[acyl-carrier-protein] synthase I
|
–
|
|
|
MetaCyc:
2.3.1.41-RXN
|
|
|
|
[acyl-carrier_protein] + S-acetylphosphopantetheine <=> acetyl-[acyl-carrier_protein] + 4''-phosphopantetheine
|
2.3.1.49
deacetyl-[citrate-(pro-3S)-lyase] S-acetyltransferase
|
–
|
M
|
|
MetaCyc:
2.3.1.49-RXN
|
|
|
|
2,3,4-saturated_fatty_acyl-[acp] + malonyl-[acyl-carrier_protein] + H+ <=> 3-oxoacyl-[acyl-carrier_protein] + CO2 + [acyl-carrier_protein]
|
2.3.1.179
beta-ketoacyl-[acyl-carrier-protein] synthase II
2.3.1.41
beta-ketoacyl-[acyl-carrier-protein] synthase I
|
–
–
|
M
|
|
MetaCyc:
3-OXOACYL-ACP-SYNTH-RXN
|
|
|
|
S-adenosyl-L-methionine + (3R)-3-hydroxybutanoyl-[acyl-carrier_protein] <=> [acyl-carrier_protein] + S-methyl-5''-thioadenosine + N-3-hydroxybutanoyl-L-homoserine_lactone + H+
|
2.3.1.184
acyl-homoserine-lactone synthase
|
–
|
|
|
MetaCyc:
RXN-10026
|
|
|
|
(5Z)-dodec-5-enoyl-[ACP] + malonyl-[acyl-carrier_protein] + H+ <=> (7Z)-3-oxotetradec-7-enoyl-[acp] + [acyl-carrier_protein] + CO2
|
2.3.1.179
beta-ketoacyl-[acyl-carrier-protein] synthase II
2.3.1.41
beta-ketoacyl-[acyl-carrier-protein] synthase I
|
–
–
|
M
|
|
MetaCyc:
RXN-10654
|
|
|
|
(7Z)-tetradec-7-enoyl-[acp] + malonyl-[acyl-carrier_protein] + H+ <=> (9Z)-3-oxohexadec-9-enoyl-[acp] + [acyl-carrier_protein] + CO2
|
2.3.1.179
beta-ketoacyl-[acyl-carrier-protein] synthase II
2.3.1.41
beta-ketoacyl-[acyl-carrier-protein] synthase I
|
–
–
|
M
|
|
MetaCyc:
RXN-10658
|
|
|
|
hexadecanal + [acyl-carrier_protein] + NAD+ <=> palmitoyl-[acyl-carrier_protein] + NADH + H+
|
1.2.1.80
long-chain acyl-[acyl-carrier-protein] reductase
|
–
|
|
|
MetaCyc:
RXN-11706_WOP
|
|
|
|
(3R)-3-hydroxyacyl-[acyl-carrier_protein] + H2O <=> 3-(3-hydroxyalkanoyloxy)alkanoate + [acyl-carrier_protein] + H+
|
not assigned
|
–
|
M
|
|
MetaCyc:
RXN-11762
|
|
|
|
(3R)-3-hydroxyacyl-[acyl-carrier_protein] + CoA <=> (3R)-3-hydroxyacyl-CoA + [acyl-carrier_protein]
|
2.4.1
|
–
|
|
|
MetaCyc:
RXN-11785
|
|
|
|
(3R)-3-hydroxydecanoyl-[acyl-carrier_protein] + CoA <=> (3R)-3-hydroxydecanoyl-CoA + [acyl-carrier_protein]
|
2.4.1
|
–
|
M
|
|
MetaCyc:
RXN-11797
|
|
|
|
malonate + [acyl-carrier_protein] + ATP <=> malonyl-[acyl-carrier_protein] + AMP + diphosphate
|
6.2.1
|
–
|
M
|
|
MetaCyc:
RXN-12360
|
|
|
|
malonyl-[acyl-carrier_protein] + H+ <=> acetoacetyl-[acyl-carrier_protein] + CO2 + [acyl-carrier_protein]
|
2.3.1
|
–
|
M
|
|
MetaCyc:
RXN-12361
|
|
|
|
dihomo_gamma_linolenoyl_[acp] + H2O <=> 8,11,14-eicosatrienoic_acid + [acyl-carrier_protein] + H+
|
3.1.2.14
oleoyl-[acyl-carrier-protein] hydrolase
|
–
|
|
|
MetaCyc:
RXN-12973
|
|
|
|
gamma-linolenoyl-CoA + [acyl-carrier_protein] <=> gamma_linolenoyl_[acp] + CoA
|
not assigned
|
–
|
|
|
MetaCyc:
RXN-12974
|
|
|
|
docosapentaenoyl_[acp] + H2O <=> docosapentaenoic_acid + [acyl-carrier_protein] + H+
|
3.1.2.14
oleoyl-[acyl-carrier-protein] hydrolase
|
–
|
|
|
MetaCyc:
RXN-13011
|
|
|
|
octanoyl-[acyl-carrier_protein] + [glycine_cleavage_system_lipoyl-carrier_protein]-L-lysine <=> [glycine-cleavage_complex_H_protein]_N6-octanoyl-L-lysine + [acyl-carrier_protein] + H+
|
2.3.1.181
lipoyl(octanoyl) transferase
|
–
|
M
|
|
MetaCyc:
RXN-13037
|
|
|
|
palmitoyl-[acyl-carrier_protein] + malonyl-CoA <=> 1-heptadecene + CO2 + [acyl-carrier_protein] + CoA
|
2.3.1
|
–
|
|
|
MetaCyc:
RXN-13258
|
|
|
|
heptodecanoyl-[acp] + malonyl-CoA + H+ + reduced_acceptor <=> 1-octadecene + CO2 + [acyl-carrier_protein] + CoA + acceptor
|
2.3.1
|
–
|
|
|
MetaCyc:
RXN-13259
|
|
|
|
acyl-[acyl-carrier_protein] + malonyl-CoA + reduced_acceptor + H+ <=> terminal_olefin + CO2 + [acyl-carrier_protein] + CoA + acceptor
|
2.3.1
|
–
|
M
|
|
MetaCyc:
RXN-13260
|
|
|
|
stearoyl-[acyl-carrier_protein] + malonyl-CoA + H+ <=> 1-nonadecene + CO2 + [acyl-carrier_protein] + CoA
|
2.3.1
|
–
|
|
|
MetaCyc:
RXN-13261
|
|
|
|
3-oxotetradecanoyl-[acyl-carrier_protein] + H2O <=> 3-oxotetradecanoate + [acyl-carrier_protein] + H+
|
3.1.2
|
–
|
M
|
|
MetaCyc:
RXN-15280
|
|
|
|
3-oxododecanoyl-[acyl-carrier_protein] + H2O <=> 3-Oxododecanoate + [acyl-carrier_protein] + H+
|
3.1.2
|
–
|
M
|
|
MetaCyc:
RXN-15281
|
|
|
|
3-oxohexadecanoyl-[acyl-carrier_protein] + H2O <=> 3-oxo-palmitate + [acyl-carrier_protein] + H+
|
3.1.2
|
–
|
M
|
|
MetaCyc:
RXN-15282
|
|
|
|
acetyl-CoA + malonyl-CoA + [acyl-carrier_protein] + H+ <=> acetoacetyl-[acyl-carrier_protein] + CoA + CO2
|
2.3.1
|
–
|
M
|
|
MetaCyc:
RXN-15810
|
|
|
|
acetoacetyl-[acyl-carrier_protein] + L-tryptophan + ATP <=> cyclo-acetoacetyl-L-tryptophan + AMP + diphosphate + [acyl-carrier_protein] + H+
|
6.3.2
|
–
|
M
|
|
MetaCyc:
RXN-15811
|
|
|
|
6,8-dimethyl-3-oxo-4,6-decadienoyl-[acp] + L-tyrosine + ATP <=> pretenellin_A + [acyl-carrier_protein] + H+ + AMP + diphosphate
|
6.3.2
|
–
|
M
|
|
MetaCyc:
RXN-15883
|
|
|
|
S-adenosyl-L-methionine + malonyl-CoA + acetyl-CoA + [acyl-carrier_protein] + NADPH + H+ <=> 6,8-dimethyl-3-oxo-4,6-decadienoyl-[acp] + S-adenosyl-L-homocysteine + CoA + CO2 + H2O + NADP+
|
2.3.1
|
–
|
M
|
|
MetaCyc:
RXN-15885
|
|
|
|
S-adenosyl-L-methionine + malonyl-CoA + acetyl-CoA + NADPH + H+ + [acyl-carrier_protein] <=> 10-methyl-3-oxo-4,6,8-dodecatrienoyl-[acp] + NADP+ + CoA + S-adenosyl-L-homocysteine + CO2 + H2O
|
2.3.1
|
–
|
M
|
|
MetaCyc:
RXN-15894
|
|
|
|
10-methyl-3-oxo-4,6,8-dodecatrienoyl-[acp] + ATP + L-tyrosine <=> predesmethylbassianin_A + AMP + diphosphate + [acyl-carrier_protein] + H+
|
6.3.2
|
–
|
M
|
|
MetaCyc:
RXN-15895
|
|
|
|
S-adenosyl-L-methionine + malonyl-CoA + acetyl-CoA + [acyl-carrier_protein] + NADPH + H+ <=> 8,10-dimethyl-3-oxo-4,6,8-dodecatrienoyl-[acp] + CoA + S-adenosyl-L-homocysteine + CO2 + H2O + NADP+
|
2.3.1
|
–
|
M
|
|
MetaCyc:
RXN-15897
|
|
|
|
8,10-dimethyl-3-oxo-4,6,8-dodecatrienoyl-[acp] + ATP + L-tyrosine <=> prebassianin_A + AMP + diphosphate + [acyl-carrier_protein] + H+
|
6.3.2
|
–
|
M
|
|
MetaCyc:
RXN-15898
|
|
|
|
S-adenosyl-L-methionine + acetyl-CoA + malonyl-CoA + NADPH + H+ + [acyl-carrier_protein] <=> 4,6-dimethyl-3-oxooctanoyl-[acp] + NADP+ + CoA + S-adenosyl-L-homocysteine + H2O + CO2
|
2.3.1
|
–
|
M
|
|
MetaCyc:
RXN-15917
|
|
|
|
S-adenosyl-L-methionine + acetyl-CoA + malonyl-CoA + NADH + H+ + [acyl-carrier_protein] <=> 4,6-dimethyl-3-oxooctanoyl-[acp] + NAD+ + CoA + S-adenosyl-L-homocysteine + H2O + CO2
|
2.3.1
|
–
|
|
|
MetaCyc:
RXN-15917_WOP
|
|
|
|
4,6-dimethyl-3-oxooctanoyl-[acp] + L-tyrosine + ATP <=> preaspyridone_A + AMP + diphosphate + [acyl-carrier_protein] + H+
|
6.3.2
|
–
|
M
|
|
MetaCyc:
RXN-15918
|
|
|
|
palmitoyl-[acyl-carrier_protein] + 1-stearoyl-sn-glycerol_3-phosphate <=> 1-stearoyl-2-palmitoyl-sn-glycerol_3-phosphate + [acyl-carrier_protein]
|
2.3.1.51
1-acylglycerol-3-phosphate O-acyltransferase
|
–
|
|
|
MetaCyc:
RXN-16025
|
|
|
|
acyl-[acyl-carrier_protein] + 1-stearoyl-sn-glycerol_3-phosphate <=> 1-stearoyl-2-acyl-sn-glycerol_3-phosphate + [acyl-carrier_protein]
|
2.3.1.51
1-acylglycerol-3-phosphate O-acyltransferase
|
–
|
M
|
|
MetaCyc:
RXN-16067
|
|
|
|
acyl-[acyl-carrier_protein] + 2-acyl-sn-glycerol_3-phosphate <=> phosphatidic_acid + [acyl-carrier_protein]
|
2.3.1
|
–
|
|
|
MetaCyc:
RXN-16075
|
|
|
|
stearoyl-[acyl-carrier_protein] + 1-stearoyl-sn-glycerol_3-phosphate <=> 1-stearoyl-2-stearoyl-sn-glycerol_3-phosphate + [acyl-carrier_protein]
|
2.3.1.51
1-acylglycerol-3-phosphate O-acyltransferase
|
–
|
|
|
MetaCyc:
RXN-16076
|
|
|
|
oleoyl-[acyl-carrier_protein] + 1-stearoyl-sn-glycerol_3-phosphate <=> 1-stearoyl-2-oleoyl-sn-glycerol-3-phosphate + [acyl-carrier_protein]
|
2.3.1.51
1-acylglycerol-3-phosphate O-acyltransferase
|
–
|
|
|
MetaCyc:
RXN-16077
|
|
|
|
S-adenosyl-L-methionine + acetyl-CoA + malonyl-CoA + [acyl-carrier_protein] + NADPH + H+ <=> 8,10,16-trimethyl-3-oxooctadeca-4,8,12,14,16-pentaenoyl-[acp] + S-adenosyl-L-homocysteine + CoA + CO2 + NADP+ + H2O
|
2.3.1
|
–
|
M
|
|
MetaCyc:
RXN-16180
|
|
|
|
8,10,16-trimethyl-3-oxooctadeca-4,8,12,14,16-pentaenoyl-[acp] + L-tryptophan + ATP + NADPH <=> prochaetoglobosin_I + [acyl-carrier_protein] + AMP + diphosphate + H2O + NADP+
|
6.3.2
|
–
|
M
|
|
MetaCyc:
RXN-16181
|
|
|
|
hex-5-enoic_acid + [acyl-carrier_protein] + ATP <=> 5-hexenoyl-[acp] + AMP + diphosphate
|
6.2.1.47
medium-chain-fatty-acid---[acyl-carrier-protein] ligase
|
–
|
|
|
MetaCyc:
RXN-16463
|
|
|
|
medium_chain_fatty_acid + [acyl-carrier_protein] + ATP <=> medium-chain_fatty_acyl-[acp] + AMP + diphosphate
|
6.2.1.47
medium-chain-fatty-acid---[acyl-carrier-protein] ligase
|
–
|
|
|
MetaCyc:
RXN-16469
|
|
|
|
linoleyl-AMP + [acyl-carrier_protein] <=> linoleyl-[acp] + AMP + H+
|
6.1
|
–
|
M
|
|
MetaCyc:
RXN-16499
|
|
|
|
lineolate-L-ornithine-L-threonine-trans-hydroxy-L-proline-3-hydroxy-L-homotyrosine-L-threonine-4-methyl-3-hydroxy-prolyl-[acp] <=> echinocandin_D + [acyl-carrier_protein] + H+
|
6.3.2
|
–
|
M
|
|
MetaCyc:
RXN-16506
|
|
|
|
acetyl-CoA + malonyl-CoA + [acyl-carrier_protein] + H+ <=> 1-(2,4-dihydroxy-6-methylphenyl)octane-1,3,5,7-tetrone-[acp] + CoA + CO2 + H2O
|
2.3.1
|
–
|
M
|
|
MetaCyc:
RXN-16531
|
|
|
|
1-(2,4-dihydroxy-6-methylphenyl)octane-1,3,5,7-tetrone-[acp] <=> 2-(2,4-dihydroxy-6-methylbenzoyl)benzene-1,3,5-triol + [acyl-carrier_protein]
|
2.3.1
|
–
|
M
|
|
MetaCyc:
RXN-16532
|
|
|
|
Malonamoyl-CoA + malonyl-CoA + [acyl-carrier_protein] + H+ <=> 4-(3-acetyl-2,5,7,10-tetrahydroxy-4-oxo-3-hydroanthracen-2-yl)-3-oxobutanamyl-[acp] + CoA + CO2 + H2O
|
2.3.1
|
–
|
M
|
|
MetaCyc:
RXN-16577
|
|
|
|
4-(3-acetyl-2,5,7,10-tetrahydroxy-4-oxo-3-hydroanthracen-2-yl)-3-oxobutanamyl-[acp] <=> 12a-deshydroxy-desmethylanthrotainin + [acyl-carrier_protein] + H+
|
not assigned
|
–
|
M
|
|
MetaCyc:
RXN-16578
|
|
|
|
2-aminoisobutanoate + ATP + [acyl-carrier_protein] <=> 2-aminoisobutanoyl-[acp] + AMP + diphosphate
|
6.2.1
|
–
|
M
|
|
MetaCyc:
RXN-16584
|
|
|
|
fumiquinazoline_F-indoline-3''-ol-2''-2-aminoisobutanoyl-[acp] <=> 15,15-dimethyl-2-epi-fumiquinazoline_A + [acyl-carrier_protein]
|
not assigned
|
–
|
M
|
|
MetaCyc:
RXN-16586
|
|
|
|
(3Z)-dodec-3-enoyl-[acp] + malonyl-[acyl-carrier_protein] + H+ <=> (5Z)-3-oxo-tetradec-5-enoyl-[acp] + [acyl-carrier_protein] + CO2
|
2.3.1.179
beta-ketoacyl-[acyl-carrier-protein] synthase II
2.3.1.41
beta-ketoacyl-[acyl-carrier-protein] synthase I
|
–
–
|
M
|
|
MetaCyc:
RXN-16615
|
|
|
|
(5Z)-tetradec-5-enoyl-[acp] + malonyl-[acyl-carrier_protein] + H+ <=> (7Z)-3-oxo-hexadec-7-enoyl-[acp] + [acyl-carrier_protein] + CO2
|
2.3.1.179
beta-ketoacyl-[acyl-carrier-protein] synthase II
2.3.1.41
beta-ketoacyl-[acyl-carrier-protein] synthase I
|
–
–
|
M
|
|
MetaCyc:
RXN-16621
|
|
|
|
(7Z)-hexadec-7-enoyl-[acp] + malonyl-[acyl-carrier_protein] + H+ <=> (9Z)-3-oxo-octadec-9-enoyl-[acp] + [acyl-carrier_protein] + CO2
|
2.3.1.179
beta-ketoacyl-[acyl-carrier-protein] synthase II
2.3.1.41
beta-ketoacyl-[acyl-carrier-protein] synthase I
|
–
–
|
M
|
|
MetaCyc:
RXN-16625
|
|
|
|
oleoyl-[acyl-carrier_protein] + malonyl-[acyl-carrier_protein] + H+ <=> (11Z)-3-oxo-icos-11-enoyl-[acp] + [acyl-carrier_protein] + CO2
|
2.3.1.179
beta-ketoacyl-[acyl-carrier-protein] synthase II
2.3.1.41
beta-ketoacyl-[acyl-carrier-protein] synthase I
|
–
–
|
M
|
|
MetaCyc:
RXN-16629
|
|
|
|
2-hydroxyisocaproate + [acyl-carrier_protein] + ATP <=> R-2-hydroxy-3-methylpentanoyl-[acp] + AMP + diphosphate
|
6.3.2
|
–
|
M
|
|
MetaCyc:
RXN-16636
|
|
|
|
R-Hmp-MeVal-Phe-MePhe-Pro-alle-MeVal-Leu-MeVal-[acp] <=> aureobasidin_A + [acyl-carrier_protein]
|
6.3.2
|
–
|
M
|
|
MetaCyc:
RXN-16646
|
|
|
|
L-pipecolic_acid + [acyl-carrier_protein] + ATP <=> D-pipecolyl-[acp] + AMP + diphosphate
|
6.3.2
|
–
|
M
|
|
MetaCyc:
RXN-16682
|
|
|
|
apicidin-[acp] <=> apicidin + [acyl-carrier_protein]
|
6.3.2
|
–
|
M
|
|
MetaCyc:
RXN-16684
|
|
|
|
apicidin_F-[acp] <=> apicidin_F + [acyl-carrier_protein]
|
6.3.2
|
–
|
M
|
|
MetaCyc:
RXN-16686
|
|
|
|
S-adenosyl-L-methionine + malonyl-CoA + [acyl-carrier_protein] + NADPH + H+ <=> 1-[(1S,2R,4aS,6R,8aR)-1,6-dimethyl-2-[(1E)-prop-1-en-1-yl)]-1,2,4a,5,6,7,8,8a-octahydronaphthalen-1-yl]butane-1,3-dioyl-[acp] + CoA + S-adenosyl-L-homocysteine + NADP+ + CO2 + H2O
|
2.3.1
|
–
|
M
|
|
MetaCyc:
RXN-16692
|
|
|
|
1-[(1S,2R,4aS,6R,8aR)-1,6-dimethyl-2-[(1E)-prop-1-en-1-yl)]-1,2,4a,5,6,7,8,8a-octahydronaphthalen-1-yl]butane-1,3-dioyl-[acp] + L-serine + ATP <=> trichosetin + [acyl-carrier_protein] + AMP + diphosphate + H+
|
6.3.2
|
–
|
M
|
|
MetaCyc:
RXN-16693
|
|
|
|
S-adenosyl-L-methionine + acetyl-CoA + malonyl-CoA + [acyl-carrier_protein] + NADPH + H+ <=> (5E,7E,9E,11E,13E)-3,7,11,13-tetramethylpentadeca-5,7,9,11,13-pentaene-2,4-dioyl-[acp] + CoA + S-adenosyl-L-homocysteine + CO2 + NADP+ + H2O
|
2.3.1
|
–
|
M
|
|
MetaCyc:
RXN-16698
|
|
|
|
(5E,7E,9E,11E,13E)-3,7,11,13-tetramethylpentadeca-5,7,9,11,13-pentaene-2,4-dioyl-[acp] + L-tyrosine + ATP <=> fusaridione_A + [acyl-carrier_protein] + AMP + diphosphate + H+
|
6.3.2
|
–
|
M
|
|
MetaCyc:
RXN-16699
|
|
|
|
acetyl-CoA + [acyl-carrier_protein] + NADPH + H+ <=> triketide-[acp] + CoA + CO2 + H2O + NADP+
|
2.3.1
|
–
|
M
|
|
MetaCyc:
RXN-16717
|
|
|
|
triketide-[acp] + oxaloacetate + NH3 <=> fusarate + H2O + [acyl-carrier_protein]
|
not assigned
|
–
|
M
|
|
MetaCyc:
RXN-16718
|
|
|
|
S-adenosyl-L-methionine + acetyl-CoA + malonyl-CoA + [acyl-carrier_protein] + NADPH + H+ <=> (5E,7E,9E,11E,13Z)-5,9,11,13-tetramethylpentadeca-5,7,9,11,13-pentaene-2,4-dioyl-[acp] + CoA + S-adenosyl-L-homocysteine + CO2 + NADP+ + H2O
|
2.3.1
|
–
|
M
|
|
MetaCyc:
RXN-16738
|
|
|
|
(5E,7E,9E,11E,13Z)-5,9,11,13-tetramethylpentadeca-5,7,9,11,13-pentaene-2,4-dioyl-[acp] + L-homoserine + ATP + NADPH <=> prefusarin + [acyl-carrier_protein] + AMP + diphosphate + NADP+ + H2O
|
6.3.2
|
–
|
M
|
|
MetaCyc:
RXN-16739
|
|
|
|
propanoyl-[acp] + malonyl-CoA + H2O + H+ <=> 3,5,7,9,11,13,15,17,19-nonaoxohenicosanoate + [acyl-carrier_protein] + CoA + CO2
|
2.3.1
|
–
|
|
|
MetaCyc:
RXN-16843
|
|
|
|
acetyl-CoA + malonyl-CoA + [acyl-carrier_protein] + H+ <=> pentadecane-2,4,6,8,10,12,14-heptonyl-[acp] + CoA + CO2
|
2.3.1
|
–
|
M
|
|
MetaCyc:
RXN-16855
|
|
|
|
pentadecane-2,4,6,8,10,12,14-heptonyl-[acp] + NADPH + H+ <=> 6-O-demethylfusarubinaldehyde + [acyl-carrier_protein] + H2O + NADP+
|
2.3.1
|
–
|
M
|
|
MetaCyc:
RXN-16856
|
|
|
|
pentadecane-2,4,6,8,10,12,14-heptonyl-[acp] + NADH + H+ <=> 6-O-demethylfusarubinaldehyde + [acyl-carrier_protein] + H2O + NAD+
|
2.3.1
|
–
|
|
|
MetaCyc:
RXN-16856_WOP
|
|
|
|
malonyl-CoA + [acyl-carrier_protein] + H+ <=> nonadecane-2,4,6,8,10,12,14,16,18-nononyl-[acp] + CoA + CO2
|
2.3.1
|
–
|
M
|
|
MetaCyc:
RXN-16882
|
|
|
|
nonadecane-2,4,6,8,10,12,14,16,18-nononyl-[acp] <=> pre-bikaverin + [acyl-carrier_protein] + H2O
|
2.3.1
|
–
|
M
|
|
MetaCyc:
RXN-16883
|
|
|
|
Guanidinoacetate + aminomalonyl-[L-seryl-carrier_protein] + malonyl-[acyl-carrier_protein] + Carbamoyl_phosphate + H+ + NADPH + L-glutamate <=> (2S,3S,7R)-2,3-diamino-8-(1-carbamoyl-2-iminoimidazolidin-4-yl)-7-hydroxyoctanoate + [acyl-carrier_protein] + holo-[L-seryl-carrier_protein] + phosphate + CO2 + H2O + NADP+ + 2-oxoglutarate
|
2.3.1
|
–
|
|
|
MetaCyc:
RXN-16911
|
|
|
|
[acyl-carrier_protein] + 3-phospho-D-glyceroyl_phosphate + H2O <=> D-glyceryl-[acp] + phosphate
|
2.3.1
|
–
|
M
|
|
MetaCyc:
RXN-16914
|
|
|
|
fatty_acid + L-asparagine + L-serine + malonyl-CoA + aminomalonyl-[L-seryl-carrier_protein] + (2R)-2-hydroxymalonyl-[acp] + L-Albizziin + L-alanine + O2 + NADPH + H+ + polyketide-[acp] <=> proto-zwittermicin_A-L-alanyl-[PKS] + CO2 + NADP+ + H2O + holo-[L-seryl-carrier_protein] + [acyl-carrier_protein] + CoA
|
2.3.1
|
–
|
M
|
|
MetaCyc:
RXN-16919
|
|
|
|
acetyl-CoA + malonyl-CoA + [acyl-carrier_protein] + H+ <=> 3,5,7,9,11,13-hexaoxotetradecanoyl-[acp] + CoA + CO2
|
2.3.1
|
–
|
M
|
|
MetaCyc:
RXN-16920
|
|
|
|
3,5,7,9,11,13-hexaoxotetradecanoyl-[acp] <=> YWA1 + [acyl-carrier_protein] + H2O
|
2.3.1
|
–
|
M
|
|
MetaCyc:
RXN-16921
|
|
|
|
NADPH + H+ + 2,4-dihydroxy_6-(2,4,6-trioxoheptyl)benzoyl-[acp] <=> citreoisocoumarin + [acyl-carrier_protein] + NADP+
|
2.3.1
|
–
|
M
|
|
MetaCyc:
RXN-16932
|
|
|
|
NADH + H+ + 2,4-dihydroxy_6-(2,4,6-trioxoheptyl)benzoyl-[acp] <=> citreoisocoumarin + [acyl-carrier_protein] + NAD+
|
2.3.1
|
–
|
|
|
MetaCyc:
RXN-16932_WOP
|
|
|
|
2-[4-(2,4-dihydroxy-6-methylphenyl)-2,4-dioxobutyl]-4,6-dihydroxybenzoyl-[acp] <=> bikisocoumarin + [acyl-carrier_protein]
|
2.3.1
|
–
|
M
|
|
MetaCyc:
RXN-16933
|
|
|
|
S-adenosyl-L-methionine + malonyl-CoA + acetyl-CoA + [acyl-carrier_protein] + NADPH + H+ <=> (5E,7S,9S,11,E,13E,15E)-7,9,15-trimethylheptadeca-5,11,13,15-tetraene-2,4-dionyl-[acp] + CoA + S-adenosyl-L-homocysteine + CO2 + NADP+ + H2O
|
2.3.1
|
–
|
M
|
|
MetaCyc:
RXN-16959
|
|
|
|
S-adenosyl-L-methionine + malonyl-CoA + acetyl-CoA + [acyl-carrier_protein] + NADH + H+ <=> (5E,7S,9S,11,E,13E,15E)-7,9,15-trimethylheptadeca-5,11,13,15-tetraene-2,4-dionyl-[acp] + CoA + S-adenosyl-L-homocysteine + CO2 + NAD+ + H2O
|
2.3.1
|
–
|
|
|
MetaCyc:
RXN-16959_WOP
|
|
|
|
(5E,7S,9S,11,E,13E,15E)-7,9,15-trimethylheptadeca-5,11,13,15-tetraene-2,4-dionyl-[acp] + 4-Hydroxy-4-methylglutamate + ATP <=> 3-[(2R)-3,5-dioxo-4-[(2E.4S,6S,8E,10E,12E)-4,6,12-trimethyltetradeca-2,8,10,12-tetraenoyl]pyrrolidin-2-yl]-2-hydroxy-2-methylpropanoate + [acyl-carrier_protein] + AMP + diphosphate + H+
|
6.3.2
|
–
|
M
|
|
MetaCyc:
RXN-16960
|
|
|
|
palmitoleoyl-[acyl-carrier_protein] + 1-palmitoyl-sn-glycerol_3-phosphate <=> 1-palmitoyl-2-palmitoleoyl-sn-glycerol_3-phosphate + [acyl-carrier_protein]
|
2.3.1.51
1-acylglycerol-3-phosphate O-acyltransferase
|
–
|
|
|
MetaCyc:
RXN-17012
|
|
|
|
palmitoleoyl-[acyl-carrier_protein] + 1-cis-vaccenoyl-sn-glycerol_3-phosphate <=> 1-cis-vaccenoyl-2-palmitoleoyl-sn-glycerol-3-phosphate + [acyl-carrier_protein]
|
2.3.1.51
1-acylglycerol-3-phosphate O-acyltransferase
|
–
|
|
|
MetaCyc:
RXN-17013
|
|
|
|
cis-vaccenoyl-[acyl-carrier_protein] + 1-palmitoyl-sn-glycerol_3-phosphate <=> 1-palmitoyl-2-cis-vaccenoyl_phosphatidate + [acyl-carrier_protein]
|
2.3.1.51
1-acylglycerol-3-phosphate O-acyltransferase
|
–
|
|
|
MetaCyc:
RXN-17014
|
|
|
|
cis-vaccenoyl-[acyl-carrier_protein] + 1-cis-vaccenoyl-sn-glycerol_3-phosphate <=> 1,2-bis-cis-vaccenoyl-phosphatidate + [acyl-carrier_protein]
|
2.3.1.51
1-acylglycerol-3-phosphate O-acyltransferase
|
–
|
|
|
MetaCyc:
RXN-17015
|
|
|
|
tetradecanoyl-[acyl-carrier_protein] + sn-glycerol_3-phosphate <=> 1-myristoyl-sn-glycerol_3-phosphate + [acyl-carrier_protein]
|
2.3.1.15
glycerol-3-phosphate 1-O-acyltransferase
|
–
|
|
|
MetaCyc:
RXN-17017
|
|
|
|
palmitoleoyl-[acyl-carrier_protein] + 1-myristoyl-sn-glycerol_3-phosphate <=> 1-myristoyl-2-palmitoleoyl-sn-glycerol_3-phosphate + [acyl-carrier_protein]
|
2.3.1.51
1-acylglycerol-3-phosphate O-acyltransferase
|
–
|
|
|
MetaCyc:
RXN-17020
|
|
|
|
tetradecanoyl-[acyl-carrier_protein] + 1-myristoyl-sn-glycerol_3-phosphate <=> 1,2-dimyristoyl-sn-glycero-3-phosphate + [acyl-carrier_protein]
|
2.3.1.51
1-acylglycerol-3-phosphate O-acyltransferase
|
–
|
|
|
MetaCyc:
RXN-17022
|
|
|
|
1-palmitoyl-sn-glycerol_3-phosphate + tetradecanoyl-[acyl-carrier_protein] <=> 1-palmitoyl-2-myristoyl_phosphatidate + [acyl-carrier_protein]
|
2.3.1.51
1-acylglycerol-3-phosphate O-acyltransferase
|
–
|
|
|
MetaCyc:
RXN-17024
|
|
|
|
3-oxoacyl-[acyl-carrier_protein] + H2O <=> a_3-oxo_acid + [acyl-carrier_protein] + H+
|
3.1.2
|
–
|
|
|
MetaCyc:
RXN-17836
|
|
|
|
acyl-[acyl-carrier_protein] + N-acetyl-D-glucosaminyl-tunicaminyl-uracil <=> tunicamycin + [acyl-carrier_protein] + H+
|
2.3.1.M33
|
–
|
M
|
|
MetaCyc:
RXN-18074
|
|
|
|
8-methyl-3-oxononanoyl-[acp] + dihydroxyacetone_phosphate <=> 2-oxo-3-(phosphooxy)propyl_8-methyl-3-oxononanoate + [acyl-carrier_protein]
|
2.3.1.277
2-oxo-3-(phosphooxy)propyl 3-oxoalkanoate synthase
|
–
|
M
|
|
MetaCyc:
RXN-18614
|
|
|
|
7-methyl-3-oxooctanoyl-[acp] + dihydroxyacetone_phosphate <=> 2-oxo-3-(phosphooxy)propyl_7-methyl-3-oxooctanoate + [acyl-carrier_protein]
|
2.3.1.277
2-oxo-3-(phosphooxy)propyl 3-oxoalkanoate synthase
|
–
|
|
|
MetaCyc:
RXN-18639
|
|
|
|
(3R)-3-hydroxyhexadecanoyl-[acp] + glycine <=> commendamide + [acyl-carrier_protein] + H+
|
2.3.1
|
–
|
M
|
|
MetaCyc:
RXN-19519
|
|
|
|
ultra-long-chain_mono-unsaturated_acyl-[acp] + malonyl-[acyl-carrier_protein] + H+ <=> ultra-long-chain_mono-unsaturated_3-oxo-fatty_acyl-[acp] + [acyl-carrier_protein] + CO2
|
2.3.1.293
meromycolic acid 3-oxoacyl-(acyl carrier protein) synthase I
|
–
|
|
|
MetaCyc:
RXN-19846
|
|
|
|
ultra-long-chain_di-unsaturated_fattyl_acyl-[acp] + malonyl-[acyl-carrier_protein] + H+ <=> an_ultra-long-chain_di-unsaturated_3-oxo-fatty_acyl-[acyl-carrier_protein] + [acyl-carrier_protein] + CO2
|
2.3.1.294
meromycolic acid 3-oxoacyl-(acyl carrier protein) synthase II
|
–
|
|
|
MetaCyc:
RXN-19847
|
|
|
|
S-adenosyl-L-methionine + soluble_holo-[acyl-carrier_protein] + acetyl-[acyl-carrier_protein] + malonyl-[acyl-carrier_protein] + NADPH + H+ <=> (3S,4R,6E,8R,9S)-3,9-dihydroxy-4,8-dimethyldec-6-enoyl-[acp] + CO2 + S-adenosyl-L-homocysteine + NADP+ + H2O + [acyl-carrier_protein]
|
2.3.1.M60
|
–
|
M
|
|
MetaCyc:
RXN-19848
|
|
|
|
(3S,4R,6E,8R,9S)-3,9-dihydroxy-4,8-dimethyldec-6-enoyl-[acp] + malonyl-[acyl-carrier_protein] + NADPH + H+ <=> (5R,7S,8R,10E,12R,13S)-5,7,13-trihydroxy-8,12-dimethyl-3-oxotetradec-10-enoyl-[acp] + CO2 + [acyl-carrier_protein] + NADP+
|
2.3.1.M61
|
–
|
M
|
|
MetaCyc:
RXN-19849
|
|
|
|
(5S,6S,7R,8R,10E,12R,13S)-5,6,7,13-tetrahydroxy-8,12-dimethyl-3-oxotetradec-10-enoyl-[acp] + acetyl-[acyl-carrier_protein] + H2O <=> (5S,6S,7R,8R,10E,12R,13S)-3-(carboxymethyl)-3,5,6,7,13-pentahydroxy-8,12-dimethyltetradec-10-enoyl-[acp] + [acyl-carrier_protein] + H+
|
2.3.1.M62
|
–
|
M
|
|
MetaCyc:
RXN-19850
|
|
|
|
3-hydroxypropanoyl-[acp] + malonyl-[acyl-carrier_protein] + NADPH + H+ <=> 9-hydroxynonanoyl-[acp] + CO2 + [acyl-carrier_protein] + NADP+ + H2O
|
2.3.1.M63
|
–
|
M
|
|
MetaCyc:
RXN-19853
|
|
|
|
(2E)-3-methyl-4-[(2S,3R,4S,5R)-3,4,5-trihydroxy-5-({3-[(2S,3S)-3-hydroxybutan-2-yl]oxiran-2-yl}methyl)oxan-2-yl]but-2-enoyl-[acp] + 9-hydroxynonanoyl-[acp] + H2O <=> pseudomonate_B + [acyl-carrier_protein] + H+
|
2.3.1.M63
|
–
|
M
|
|
MetaCyc:
RXN-19860
|
|
|
|
mupirocin_P-[acp] + H2O <=> mupirocin_P + [acyl-carrier_protein] + H+
|
3.1.2.M5
|
–
|
M
|
|
MetaCyc:
RXN-19864
|
|
|
|
(2E)-3-methyl-4-[(2S,3R,4S,5R)-3,4,5-trihydroxy-5-[(2E,4R,5S)-5-hydroxy-4-methylhex-2-en-1-yl]oxan-2-yl]but-2-enoyl-[acp] + 9-hydroxynonanoyl-[acp] + H2O <=> deoxypseudomonate_B + [acyl-carrier_protein] + H+
|
2.3.1.M63
|
–
|
M
|
|
MetaCyc:
RXN-19866
|
|
|
|
deoxymupirocin_P-[acp] + H2O <=> deoxymupirocin_P + [acyl-carrier_protein] + H+
|
3.1.2.M5
|
–
|
M
|
|
MetaCyc:
RXN-19869
|
|
|
|
ATP + pseudomonate_B + [acyl-carrier_protein] <=> AMP + diphosphate + pseudomonate_B-[mAcpE]
|
6.3.2.M13
|
–
|
M
|
|
MetaCyc:
RXN-19872
|
|
|
|
ATP + deoxypseudomonate_B + [acyl-carrier_protein] <=> AMP + diphosphate + deoxypseudomonate_B-[mAcpE]
|
6.3.2.M13
|
–
|
M
|
|
MetaCyc:
RXN-19873
|
|
|
|
3-amino-5-hydroxybenzoate + ATP + [acyl-carrier_protein] <=> 3-amino-5-hydroxybenzoyl-[acyl-carrier_protein] + AMP + diphosphate
|
6.2.1.al
|
–
|
M
|
|
MetaCyc:
RXN-20315
|
|
|
|
(4S,6S,7R,8S)-7,10-dihydroxy-8-(hydroxymethyl)-2,5-diazatricyclo[7.4.0.04,6]trideca-1(9),10,12-triene-12-carboxy-[acp] + H2O <=> 9beta-mitosane_core + [acyl-carrier_protein]
|
not assigned
|
–
|
M
|
|
MetaCyc:
RXN-20321
|
|
|
|
(4S,6S,7R,8S)-7,10-dihydroxy-8-(hydroxymethyl)-2,5-diazatricyclo[7.4.0.04,6]trideca-1(9),10,12-triene-12-carboxy-[acp] + H2O <=> 9alpha-mitosane_core + [acyl-carrier_protein]
|
not assigned
|
–
|
M
|
|
MetaCyc:
RXN-20323
|
|
|
|
(3R)-3-hydroxydodecanoyl-[acp] + UDP-3-O-(3-hydroxydecanoyl)-alpha-D-glucosamine <=> UDP-2-N-[(3R)-3-hydroxydodecanoyl]-3-O-[(3R)-3-hydroxydecanoyl]-alpha-D-glucosamine + [acyl-carrier_protein] + H+
|
2.3.1.191
UDP-3-O-(3-hydroxymyristoyl)glucosamine N-acyltransferase
|
–
|
M
|
|
MetaCyc:
RXN-20787
|
|
|
|
dodecanoyl-[acyl-carrier_protein] + alpha-Kdo-(2->4)-alpha-Kdo-(2->6)-lipid_IVA_(P._putida) <=> alpha-Kdo-(2->4)-alpha-Kdo-(2->6)-(lauroyl)-lipid_IVA_(P._putida) + [acyl-carrier_protein]
|
2.3.1.241
Kdo2-lipid IVA lauroyltransferase
|
–
|
M
|
|
MetaCyc:
RXN-20792
|
|
|
|
dodecanoyl-[acyl-carrier_protein] + alpha-Kdo-(2->4)-alpha-Kdo-(2->6)-(lauroyl)-lipid_IVA_(P._putida) <=> alpha-Kdo-(2->4)-alpha-Kdo-(2->6)-lipid_A_form_C_(P._putida) + [acyl-carrier_protein]
|
2.3.1
|
–
|
M
|
|
MetaCyc:
RXN-20793
|
|
|
|
palmitoyl-[acyl-carrier_protein] + commendamide <=> N-[(3-palmitoyloxy)-palmitoyl]glycine + [acyl-carrier_protein]
|
2.3.1
|
–
|
M
|
|
MetaCyc:
RXN-20867
|
|
|
|
medium-chain_fatty_acyl-[acp] + malonyl-[acyl-carrier_protein] + H+ <=> a_medium-chain_3-oxoacyl-[acyl-carrier_protein] + CO2 + [acyl-carrier_protein]
|
2.3.1.41
beta-ketoacyl-[acyl-carrier-protein] synthase I
|
–
|
|
|
MetaCyc:
RXN-20947
|
|
|
|
(3R)-3-hydroxynonanoyl-[acp] + CoA <=> (3R)-hydroxynonanoyl-CoA + [acyl-carrier_protein]
|
2.4.1
|
–
|
|
|
MetaCyc:
RXN-21037
|
|
|
|
(4S)-4-methylhexanoyl-[acp] + malonyl-[acyl-carrier_protein] + H+ <=> (6S)-6-methyl-3-oxooctanoyl-[acp] + CO2 + [acyl-carrier_protein]
|
2.3.1.179
beta-ketoacyl-[acyl-carrier-protein] synthase II
|
–
|
M
|
|
MetaCyc:
RXN-21617
|
|
|
|
(6S)-6-methyloctanoyl-[acp] + malonyl-[acyl-carrier_protein] + H+ <=> (8S)-8-methyl-3-oxodecanoyl-[acp] + CO2 + [acyl-carrier_protein]
|
2.3.1.179
beta-ketoacyl-[acyl-carrier-protein] synthase II
|
–
|
M
|
|
MetaCyc:
RXN-21621
|
|
|
|
(8S)-8-methyldecanoyl-[acyl-carrier_protein] + malonyl-[acyl-carrier_protein] + H+ <=> (10S)-10-methyl-3-oxododecanoyl-[acp] + CO2 + [acyl-carrier_protein]
|
2.3.1.179
beta-ketoacyl-[acyl-carrier-protein] synthase II
|
–
|
M
|
|
MetaCyc:
RXN-21625
|
|
|
|
(10S)-10-methyldodecanoyl-[acp] + malonyl-[acyl-carrier_protein] + H+ <=> (12S)-12-methyl-3-oxotetradecanoyl-[acp] + CO2 + [acyl-carrier_protein]
|
2.3.1.179
beta-ketoacyl-[acyl-carrier-protein] synthase II
|
–
|
M
|
|
MetaCyc:
RXN-21629
|
|
|
|
(12S)-12-methyltetradecanoyl-[acp] + malonyl-[acyl-carrier_protein] + H+ <=> (14S)-14-methyl-3-oxohexadecanoyl-[acp] + CO2 + [acyl-carrier_protein]
|
2.3.1.179
beta-ketoacyl-[acyl-carrier-protein] synthase II
|
–
|
M
|
|
MetaCyc:
RXN-21634
|
|
|
|
(14S)-14-methylhexadecanoyl-[acp] + H2O <=> (14S)-14-methylhexadecanoate + [acyl-carrier_protein] + H+
|
3.1.2.14
oleoyl-[acyl-carrier-protein] hydrolase
|
–
|
M
|
|
MetaCyc:
RXN-21638
|
|
|
|
5-methylhexanoyl-[acp] + malonyl-[acyl-carrier_protein] + H+ <=> 7-methyl-3-oxooctanoyl-[acp] + CO2 + [acyl-carrier_protein]
|
2.3.1.179
beta-ketoacyl-[acyl-carrier-protein] synthase II
|
–
|
M
|
|
MetaCyc:
RXN-21649
|
|
|
|
7-methyloctanoyl-[acp] + malonyl-[acyl-carrier_protein] + H+ <=> 9-methyl-3-oxodecanoyl-[acp] + CO2 + [acyl-carrier_protein]
|
2.3.1.179
beta-ketoacyl-[acyl-carrier-protein] synthase II
|
–
|
M
|
|
MetaCyc:
RXN-21654
|
|
|
|
9-methyldecanoyl-[acyl-carrier_protein] + malonyl-[acyl-carrier_protein] + H+ <=> 11-methyl-3-oxododecanoyl-[acp] + CO2 + [acyl-carrier_protein]
|
2.3.1.179
beta-ketoacyl-[acyl-carrier-protein] synthase II
|
–
|
M
|
|
MetaCyc:
RXN-21659
|
|
|
|
11-methyldodecanoyl-[acp] + malonyl-[acyl-carrier_protein] + H+ <=> 13-methyl-3-oxotetradecanoyl-[acp] + CO2 + [acyl-carrier_protein]
|
2.3.1.179
beta-ketoacyl-[acyl-carrier-protein] synthase II
|
–
|
M
|
|
MetaCyc:
RXN-21664
|
|
|
|
13-methyltetradecanoyl-[acp] + malonyl-[acyl-carrier_protein] + H+ <=> 15-methyl-3-oxohexadecanoyl-[acp] + CO2 + [acyl-carrier_protein]
|
2.3.1.179
beta-ketoacyl-[acyl-carrier-protein] synthase II
|
–
|
M
|
|
MetaCyc:
RXN-21669
|
|
|
|
15-methylhexadecanoyl-[acp] + H2O <=> 15-methylhexadecanoate + [acyl-carrier_protein] + H+
|
3.1.2.14
oleoyl-[acyl-carrier-protein] hydrolase
|
–
|
M
|
|
MetaCyc:
RXN-21675
|
|
|
|
5-methylhexanoyl-[acp] + malonyl-[acyl-carrier_protein] + H+ <=> 6-methyl-3-oxoheptanoyl-[acp] + CO2 + [acyl-carrier_protein]
|
2.3.1.179
beta-ketoacyl-[acyl-carrier-protein] synthase II
|
–
|
M
|
|
MetaCyc:
RXN-21680
|
|
|
|
6-methylheptanoyl-[acp] + malonyl-[acyl-carrier_protein] + H+ <=> 8-methyl-3-oxononanoyl-[acp] + CO2 + [acyl-carrier_protein]
|
2.3.1.179
beta-ketoacyl-[acyl-carrier-protein] synthase II
|
–
|
M
|
|
MetaCyc:
RXN-21685
|
|
|
|
8-methylnonanoyl-[acyl-carrier_protein] + malonyl-[acyl-carrier_protein] + H+ <=> 1o-methyl-3-oxoundecanoyl-[acp] + CO2 + [acyl-carrier_protein]
|
2.3.1.179
beta-ketoacyl-[acyl-carrier-protein] synthase II
|
–
|
M
|
|
MetaCyc:
RXN-21690
|
|
|
|
10-methylundecanoyl-[acp] + malonyl-[acyl-carrier_protein] + H+ <=> 12-methyl-3-oxotridecanoyl-[acp] + CO2 + [acyl-carrier_protein]
|
2.3.1.179
beta-ketoacyl-[acyl-carrier-protein] synthase II
|
–
|
M
|
|
MetaCyc:
RXN-21695
|
|
|
|
12-methyltridecanoyl-[acp] + malonyl-[acyl-carrier_protein] + H+ <=> 14-methyl-3-oxopentadecanoyl-[acp] + CO2 + [acyl-carrier_protein]
|
2.3.1.179
beta-ketoacyl-[acyl-carrier-protein] synthase II
|
–
|
M
|
|
MetaCyc:
RXN-21701
|
|
|
|
14-methylpentadecanoyl-[acp] + H2O <=> 14-methylpentadecanoate + [acyl-carrier_protein] + H+
|
3.1.2.14
oleoyl-[acyl-carrier-protein] hydrolase
|
–
|
M
|
|
MetaCyc:
RXN-21706
|
|
|
|
12-methyltridecanoyl-[acp] + H2O <=> isomyristic_acid + [acyl-carrier_protein] + H+
|
3.1.2.14
oleoyl-[acyl-carrier-protein] hydrolase
|
–
|
M
|
|
MetaCyc:
RXN-21714
|
|
|
|
13-methyltetradecanoyl-[acp] + H2O <=> 13-methyltetradecanoate + [acyl-carrier_protein] + H+
|
3.1.2.14
oleoyl-[acyl-carrier-protein] hydrolase
|
–
|
M
|
|
MetaCyc:
RXN-21715
|
|
|
|
(12S)-12-methyltetradecanoyl-[acp] + H2O <=> (12S)-12-methyltetradecanoate + [acyl-carrier_protein] + H+
|
3.1.2.14
oleoyl-[acyl-carrier-protein] hydrolase
|
–
|
M
|
|
MetaCyc:
RXN-21716
|
|
|
|
(4Z)-hexadec-4-enoyl-[acp] + malonyl-[acyl-carrier_protein] + H+ <=> (6Z)-3-oxooctadec-6-enoyl-[acp] + [acyl-carrier_protein] + CO2
|
2.3.1.179
beta-ketoacyl-[acyl-carrier-protein] synthase II
|
–
|
M
|
|
MetaCyc:
RXN-8391
|
|
|
|
malonyl-[acyl-carrier_protein] + isobutyryl-CoA + NADPH + H+ <=> 8-Methyl-6-nonenoate + [acyl-carrier_protein] + CoA + H2O + NADP+
|
2.3.1
|
–
|
M
|
|
MetaCyc:
RXN-8926
|
|
|
|
petroselinoyl-[acp] + H2O <=> (6Z)-octadecenoate + [acyl-carrier_protein] + H+
|
3.1.2.14
oleoyl-[acyl-carrier-protein] hydrolase
|
–
|
M
|
|
MetaCyc:
RXN-9551
|
|
|
|
cis-vaccenoyl-[acyl-carrier_protein] + H2O <=> cis-vaccenic_acid + [acyl-carrier_protein] + H+
|
3.1.2.14
oleoyl-[acyl-carrier-protein] hydrolase
|
–
|
M
|
|
MetaCyc:
RXN-9555
|
|
|
|
[glycine_cleavage_system_lipoyl-carrier_protein]-L-lysine + Lipoyl-[acp] <=> [glycine-cleavage_complex_H_protein]_N6-[(R)-lipoyl]-L-lysine + [acyl-carrier_protein] + H+
|
not assigned
|
–
|
|
|
MetaCyc:
RXN0-1138
|
|
|
|
cis-3-decenoyl-[acyl-carrier_protein] + malonyl-[acyl-carrier_protein] + H+ <=> 3-oxo-cis-5-dodecenoyl-[acyl-carrier_protein] + [acyl-carrier_protein] + CO2
|
2.3.1.179
beta-ketoacyl-[acyl-carrier-protein] synthase II
2.3.1.41
beta-ketoacyl-[acyl-carrier-protein] synthase I
|
–
–
|
M
|
|
MetaCyc:
RXN0-2141
|
|
|
|
ATP + [acyl-carrier_protein] + 2,3,4-saturated_fatty_acid <=> 2,3,4-saturated_fatty_acyl-[acp] + AMP + diphosphate
|
6.2.1
|
–
|
|
|
MetaCyc:
RXN0-5513
|
|
|
|
2,3,4-saturated_fatty_acyl-[acp] + lysophosphatidic_acid <=> 2,3,4-saturated_1,2-diacyl-sn-glycerol_3-phosphate + [acyl-carrier_protein]
|
2.3.1.51
1-acylglycerol-3-phosphate O-acyltransferase
|
–
|
|
|
MetaCyc:
RXN0-5514
|
|
|
|
palmitoyl-[acyl-carrier_protein] + 1-palmitoyl-sn-glycerol_3-phosphate <=> 1,2-dipalmitoyl-sn-glycerol_3-phosphate + [acyl-carrier_protein]
|
2.3.1.51
1-acylglycerol-3-phosphate O-acyltransferase
|
–
|
|
|
MetaCyc:
RXN0-6705
|
|
|
|
octanoyl-[acyl-carrier_protein] + protein <=> a_[lipoyl-carrier_protein]-N6-octanoyl-L-lysine + [acyl-carrier_protein] + H+
|
2.3.1.181
lipoyl(octanoyl) transferase
|
–
|
M
|
|
MetaCyc:
RXN0-947
|
|
|
|
cis-delta17-C36:1-[acp] + malonyl-[acyl-carrier_protein] + H+ <=> cis-delta19-3-oxo-C38:1-[acp] + [acyl-carrier_protein] + CO2
|
2.3.1.293
meromycolic acid 3-oxoacyl-(acyl carrier protein) synthase I
|
–
|
M
|
|
MetaCyc:
RXN1G-1003
|
|
|
|
cis,cis-delta11,29-C48:2-[acp] + malonyl-[acyl-carrier_protein] + H+ <=> cis,cis-delta13,31-3-oxo-C50:2-[acp] + [acyl-carrier_protein] + CO2
|
2.3.1.294
meromycolic acid 3-oxoacyl-(acyl carrier protein) synthase II
|
–
|
M
|
|
MetaCyc:
RXN1G-1015
|
|
|
|
cis,cis-delta13,31-C50:2-[acp] + malonyl-[acyl-carrier_protein] + H+ <=> cis,cis-delta15,33-3-oxo-C52:2-[acp] + [acyl-carrier_protein] + CO2
|
2.3.1.294
meromycolic acid 3-oxoacyl-(acyl carrier protein) synthase II
|
–
|
M
|
|
MetaCyc:
RXN1G-1212
|
|
|
|
cis-delta19-C38:1-[acp] + malonyl-[acyl-carrier_protein] + H+ <=> cis-delta21-3-oxo-C40:1-[acp] + [acyl-carrier_protein] + CO2
|
2.3.1.293
meromycolic acid 3-oxoacyl-(acyl carrier protein) synthase I
|
–
|
M
|
|
MetaCyc:
RXN1G-132
|
|
|
|
cis-delta9-C28:1-[acp] + malonyl-[acyl-carrier_protein] + H+ <=> cis-delta11-3-oxo-C30:1-[acp] + [acyl-carrier_protein] + CO2
|
2.3.1.293
meromycolic acid 3-oxoacyl-(acyl carrier protein) synthase I
|
–
|
M
|
|
MetaCyc:
RXN1G-138
|
|
|
|
cis,cis-delta7,19-C38:2-[acp] + malonyl-[acyl-carrier_protein] + H+ <=> cis,cis-delta9,21-3-oxo-C40:2-[acp] + [acyl-carrier_protein] + CO2
|
2.3.1.294
meromycolic acid 3-oxoacyl-(acyl carrier protein) synthase II
|
–
|
M
|
|
MetaCyc:
RXN1G-172
|
|
|
|
cis,cis-delta3,15-C34:2-[acp] + malonyl-[acyl-carrier_protein] + H+ <=> cis,cis-delta5,17-3-oxo-C36:2-[acp] + [acyl-carrier_protein] + CO2
|
2.3.1.294
meromycolic acid 3-oxoacyl-(acyl carrier protein) synthase II
|
–
|
M
|
|
MetaCyc:
RXN1G-202
|
|
|
|
(7Z)-hexacos-7-enoyl-[acp] + malonyl-[acyl-carrier_protein] + H+ <=> (9Z)-3-oxooctacos-9-enoyl-[acp] + [acyl-carrier_protein] + CO2
|
2.3.1.293
meromycolic acid 3-oxoacyl-(acyl carrier protein) synthase I
|
–
|
M
|
|
MetaCyc:
RXN1G-218
|
|
|
|
cis-delta11-C30:1-[acp] + malonyl-[acyl-carrier_protein] + H+ <=> cis-delta13-3-oxo-C32:1-[acp] + [acyl-carrier_protein] + CO2
|
2.3.1.293
meromycolic acid 3-oxoacyl-(acyl carrier protein) synthase I
|
–
|
M
|
|
MetaCyc:
RXN1G-236
|
|
|
|
(3Z)-docos-3-enoyl-[acp] + malonyl-[acyl-carrier_protein] + H+ <=> (5Z)-3-oxotetracos-5-enoyl-[acp] + [acyl-carrier_protein] + CO2
|
2.3.1.293
meromycolic acid 3-oxoacyl-(acyl carrier protein) synthase I
|
–
|
M
|
|
MetaCyc:
RXN1G-26
|
|
|
|
(5Z)-tetracos-5-enoyl-[acp] + malonyl-[acyl-carrier_protein] + H+ <=> (7Z)-3-oxohexacos-7-enoyl-[acp] + [acyl-carrier_protein] + CO2
|
2.3.1.293
meromycolic acid 3-oxoacyl-(acyl carrier protein) synthase I
|
–
|
M
|
|
MetaCyc:
RXN1G-306
|
|
|
|
cis,cis-delta11,23-C42:2-[acp] + malonyl-[acyl-carrier_protein] + H+ <=> cis,cis-delta13,25-3-oxo-C44:2-[acp] + [acyl-carrier_protein] + CO2
|
2.3.1.294
meromycolic acid 3-oxoacyl-(acyl carrier protein) synthase II
|
–
|
M
|
|
MetaCyc:
RXN1G-32
|
|
|
|
cis-delta13-C32:1-[acp] + malonyl-[acyl-carrier_protein] + H+ <=> cis-delta15-3-oxo-C34:1-[acp] + [acyl-carrier_protein] + CO2
|
2.3.1.293
meromycolic acid 3-oxoacyl-(acyl carrier protein) synthase I
|
–
|
M
|
|
MetaCyc:
RXN1G-324
|
|
|
|
cis,cis-delta5,23-C42:2-[acp] + malonyl-[acyl-carrier_protein] + H+ <=> cis,cis-delta7,25-3-oxo-C44:2-[acp] + [acyl-carrier_protein] + CO2
|
2.3.1.294
meromycolic acid 3-oxoacyl-(acyl carrier protein) synthase II
|
–
|
M
|
|
MetaCyc:
RXN1G-334
|
|
|
|
malonyl-[acyl-carrier_protein] + stearoyl-[acyl-carrier_protein] + H+ <=> 3-oxo-arachidoyl-[acyl-carrier_protein] + CO2 + [acyl-carrier_protein]
|
2.3.1.41
beta-ketoacyl-[acyl-carrier-protein] synthase I
|
–
|
M
|
|
MetaCyc:
RXN1G-368
|
|
|
|
cis,cis-delta17,35-C54:2-[acp] + malonyl-[acyl-carrier_protein] + H+ <=> cis,cis-delta19,37-3-oxo-C56:2-[acp] + [acyl-carrier_protein] + CO2
|
2.3.1.294
meromycolic acid 3-oxoacyl-(acyl carrier protein) synthase II
|
–
|
M
|
|
MetaCyc:
RXN1G-374
|
|
|
|
C52-alpha-meroacyl-[acp] + ATP + H2O <=> C52-alpha-meroacyl-adenylate + diphosphate + [acyl-carrier_protein]
|
6.2.1
|
–
|
M
|
|
MetaCyc:
RXN1G-3993
|
|
|
|
cis-methoxy-C59-meroacyl-[acp] + ATP + H2O <=> cis-methoxy-C59-meroacyl-adenylate + diphosphate + [acyl-carrier_protein]
|
6.2.1
|
–
|
M
|
|
MetaCyc:
RXN1G-4140
|
|
|
|
trans-methoxy-C60-meroacyl-[acp] + ATP + H2O <=> trans-methoxy-C60-meroacyl-adenylate + diphosphate + [acyl-carrier_protein]
|
6.2.1
|
–
|
M
|
|
MetaCyc:
RXN1G-4141
|
|
|
|
cis-keto-C60-meroacyl-[acp] + ATP + H2O <=> cis-keto-C60-meroacyl-adenylate + diphosphate + [acyl-carrier_protein]
|
6.2.1
|
–
|
M
|
|
MetaCyc:
RXN1G-4142
|
|
|
|
trans-keto-C61-meroacyl-[acp] + ATP + H2O <=> trans-keto-C61-meroacyl-adenylate + diphosphate + [acyl-carrier_protein]
|
6.2.1
|
–
|
M
|
|
MetaCyc:
RXN1G-4143
|
|
|
|
cis,cis-delta13,25-C44:2-[acp] + malonyl-[acyl-carrier_protein] + H+ <=> cis,cis-delta15,27-3-oxo-C46:2-[acp] + [acyl-carrier_protein] + CO2
|
2.3.1.294
meromycolic acid 3-oxoacyl-(acyl carrier protein) synthase II
|
–
|
M
|
|
MetaCyc:
RXN1G-424
|
|
|
|
malonyl-[acyl-carrier_protein] + arachidoyl-[acp] + H+ <=> 3-oxodocosanoyl-[acp] + CO2 + [acyl-carrier_protein]
|
2.3.1.41
beta-ketoacyl-[acyl-carrier-protein] synthase I
|
–
|
M
|
|
MetaCyc:
RXN1G-445
|
|
|
|
cis,cis-delta7,25-C44:2-[acp] + malonyl-[acyl-carrier_protein] + H+ <=> cis,cis-delta9,27-3-oxo-C46:2-[acp] + [acyl-carrier_protein] + CO2
|
2.3.1.294
meromycolic acid 3-oxoacyl-(acyl carrier protein) synthase II
|
–
|
M
|
|
MetaCyc:
RXN1G-557
|
|
|
|
arachidoyl-[acp] + CoA <=> arachidoyl-CoA + [acyl-carrier_protein]
|
2.3.1
|
–
|
|
|
MetaCyc:
RXN1G-574
|
|
|
|
cis,cis-delta9,21-C40:2-[acp] + malonyl-[acyl-carrier_protein] + H+ <=> cis,cis-delta11,23-3-oxo-C42:2-[acp] + [acyl-carrier_protein] + CO2
|
2.3.1.294
meromycolic acid 3-oxoacyl-(acyl carrier protein) synthase II
|
–
|
M
|
|
MetaCyc:
RXN1G-580
|
|
|
|
cis,cis-delta19-37-C56:2-[acp] + malonyl-[acyl-carrier_protein] + H+ <=> cis,cis-delta21,39-3-oxo-C58:2-[acp] + [acyl-carrier_protein] + CO2
|
2.3.1.294
meromycolic acid 3-oxoacyl-(acyl carrier protein) synthase II
|
–
|
M
|
|
MetaCyc:
RXN1G-582
|
|
|
|
cis,cis-delta15,27-C46:2-[acp] + malonyl-[acyl-carrier_protein] + H+ <=> cis,cis-delta17,29-3-oxo-C48:2-[acp] + [acyl-carrier_protein] + CO2
|
2.3.1.294
meromycolic acid 3-oxoacyl-(acyl carrier protein) synthase II
|
–
|
M
|
|
MetaCyc:
RXN1G-660
|
|
|
|
cis,cis-delta3,21-C40:2-[acp] + malonyl-[acyl-carrier_protein] + H+ <=> cis,cis-delta5,23-3-oxo-C42:2-[acp] + [acyl-carrier_protein] + CO2
|
2.3.1.294
meromycolic acid 3-oxoacyl-(acyl carrier protein) synthase II
|
–
|
M
|
|
MetaCyc:
RXN1G-79
|
|
|
|
cis,cis-delta9,27-C46:2-[acp] + malonyl-[acyl-carrier_protein] + H+ <=> cis,cis-delta11,29-3-oxo-C48:2-[acp] + [acyl-carrier_protein] + CO2
|
2.3.1.294
meromycolic acid 3-oxoacyl-(acyl carrier protein) synthase II
|
–
|
M
|
|
MetaCyc:
RXN1G-818
|
|
|
|
cis-delta15-C34:1-[acp] + malonyl-[acyl-carrier_protein] + H+ <=> cis-delta17-3-oxo-C36:1-[acp] + [acyl-carrier_protein] + CO2
|
2.3.1.293
meromycolic acid 3-oxoacyl-(acyl carrier protein) synthase I
|
–
|
M
|
|
MetaCyc:
RXN1G-840
|
|
|
|
cis,cis-delta17,29-C48:2-[acp] + malonyl-[acyl-carrier_protein] + H+ <=> cis,cis-delta19,31-3-oxo-C50:2-[acp] + [acyl-carrier_protein] + CO2
|
2.3.1.294
meromycolic acid 3-oxoacyl-(acyl carrier protein) synthase II
|
–
|
M
|
|
MetaCyc:
RXN1G-883
|
|
|
|
cis,cis-delta5,17-C36:2-[acp] + malonyl-[acyl-carrier_protein] + H+ <=> cis,cis-delta7,19-3-oxo-C38:2-[acp] + [acyl-carrier_protein] + CO2
|
2.3.1.294
meromycolic acid 3-oxoacyl-(acyl carrier protein) synthase II
|
–
|
M
|
|
MetaCyc:
RXN1G-89
|
|
|
|
cis,cis-delta15,33-C52:2-[acp] + malonyl-[acyl-carrier_protein] + H+ <=> cis,cis-delta17,35-3-oxo-C54:2-[acp] + [acyl-carrier_protein] + CO2
|
2.3.1.294
meromycolic acid 3-oxoacyl-(acyl carrier protein) synthase II
|
–
|
M
|
|
MetaCyc:
RXN1G-94
|
|
|
|
3-oxodecanoyl-[acyl-carrier_protein] + dihydroxyacetone_phosphate <=> 2-oxo-3-(phosphooxy)propyl_3-oxodecanoate + [acyl-carrier_protein]
|
2.3.1.277
2-oxo-3-(phosphooxy)propyl 3-oxoalkanoate synthase
|
–
|
|
|
MetaCyc:
RXN1UA-47
|
|
|
|
8-methyl-3-oxodecanoyl-[acp] + dihydroxyacetone_phosphate <=> 2-oxo-3-(phosphooxy)propyl_8-methyl-3-oxodecanoate + [acyl-carrier_protein]
|
2.3.1.277
2-oxo-3-(phosphooxy)propyl 3-oxoalkanoate synthase
|
–
|
|
|
MetaCyc:
RXN1UA-66
|
|
|
|
CoA + tetradecanoyl-[acyl-carrier_protein] <=> [acyl-carrier_protein] + myristoyl-CoA
|
2.3.1
|
–
|
|
|
MetaCyc:
RXN3O-8214
|
|
|
|
dATP + fatty_acid + [acyl-carrier_protein] <=> dAMP + diphosphate + palmitoyl-[acyl-carrier_protein]
|
6.2.1.20
long-chain-fatty-acid---[acyl-carrier-protein] ligase
|
–
|
|
|
BRENDA:
BS210
|
|
|
|
acetoacetyl-CoA + [acyl-carrier_protein] <=> CoA + acetoacetyl-[acyl-carrier_protein]
|
2.3.1.39
[acyl-carrier-protein] S-malonyltransferase
|
–
|
|
|
BRENDA:
BS435198
|
|
|
|
acetoacetyl-CoA + [acyl-carrier_protein] <=> CoA + a_acetoacetyl-[acyl-carrier_protein]
|
2.3.1.85
fatty-acid synthase system
|
–
|
|
|
BRENDA:
BS455153
|
|
|
|
acetoacetyl-CoA + [acyl-carrier_protein] <=> CoA + acetoacetyl-[acyl-carrier_protein]
|
2.3.1.39
[acyl-carrier-protein] S-malonyltransferase
|
–
|
|
|
BRENDA:
BS455154
|
|
|
|
propionyl-[acyl-carrier_protein] + L-arginine <=> N-[(4S)-4-amino-5-oxoheptyl]guanidine + CO2 + [acyl-carrier_protein]
|
2.3.1.47
8-amino-7-oxononanoate synthase
|
–
|
|
|
BRENDA:
BS456305
|
|
|
|
succinyl-CoA + [acyl-carrier_protein] <=> CoA + a_succinyl-[acyl-carrier_protein]
|
2.3.1.39
[acyl-carrier-protein] S-malonyltransferase
|
–
|
|
|
BRENDA:
BS456715
|
|
|
|
succinyl-CoA + [acyl-carrier_protein] <=> CoA + a_succinyl-[acyl-carrier_protein]
|
2.3.1.85
fatty-acid synthase system
|
–
|
|
|
BRENDA:
BS456716
|
|
|
|
butyryl-CoA + [acyl-carrier_protein] <=> CoA + butyryl-[acyl-carrier_protein]
|
2.3.1.38
[acyl-carrier-protein] S-acetyltransferase
2.3.1.39
[acyl-carrier-protein] S-malonyltransferase
|
–
–
|
|
|
BRENDA:
BS320848
|
|
|
|
butyryl-CoA + [acyl-carrier_protein] <=> CoA + a_butanoyl-[acyl-carrier_protein]
|
2.3.1.85
fatty-acid synthase system
|
–
|
|
|
BRENDA:
BS455413
|
|
|
|
butyryl-CoA + [acyl-carrier_protein] <=> CoA + butyryl-[acyl-carrier_protein]
|
2.3.1.39
[acyl-carrier-protein] S-malonyltransferase
|
–
|
|
|
BRENDA:
BS455420
|
|
|
|
propionyl-[acyl-carrier_protein] + H2O <=> propionate + [acyl-carrier_protein]
|
3.1.2.2
palmitoyl-CoA hydrolase
3.1.2.20
acyl-CoA hydrolase
|
–
–
|
|
|
BRENDA:
BS360769
|
|
|
|
propionyl-CoA + [acyl-carrier_protein] <=> CoA + propionyl-[acyl-carrier_protein]
|
2.3.1.38
[acyl-carrier-protein] S-acetyltransferase
2.3.1.39
[acyl-carrier-protein] S-malonyltransferase
|
–
–
|
|
|
BRENDA:
BS320847
|
|
|
|
propionyl-CoA + [acyl-carrier_protein] <=> CoA + a_propionyl-[acyl_carrier_protein]
|
2.3.1.39
[acyl-carrier-protein] S-malonyltransferase
|
–
|
|
|
BRENDA:
BS456298
|
|
|
|
hexanoyl-CoA + [acyl-carrier_protein] <=> CoA + hexanoyl-[acyl-carrier_protein]
|
2.3.1.38
[acyl-carrier-protein] S-acetyltransferase
|
–
|
|
|
BRENDA:
BS320849
|
|
|
|
S-adenosyl-L-methionine + hexanoyl-[acyl-carrier_protein] <=> 5''-methylthioadenosine + N-hexanoyl-L-homoserine_lactone + [acyl-carrier_protein]
|
2.3.1.184
acyl-homoserine-lactone synthase
|
–
|
|
|
BRENDA:
BS380751
|
|
|
|
N-hexanoyl-[acyl-carrier_protein] + S-adenosyl-L-methionine <=> [acyl-carrier_protein] + S-methyl-5''-thioadenosine + N-hexanoyl-L-homoserine_lactone
|
2.3.1.184
acyl-homoserine-lactone synthase
|
–
|
|
|
BRENDA:
BS419482
|
|
|
|
S-adenosyl-L-methionine + 3-Hydroxybutanoyl-[acyl-carrier_protein] <=> 5''-methylthioadenosine + N-3-hydroxybutanoyl-L-homoserine_lactone + [acyl-carrier_protein]
|
2.3.1.184
acyl-homoserine-lactone synthase
|
–
|
|
|
BRENDA:
BS380744
|
|
|
|
S-adenosyl-L-methionine + 3-oxotetradecanoyl-[acyl-carrier_protein] <=> 5''-methylthioadenosine + N-(3-oxotetradecanoyl)-L-homoserine_lactone + [acyl-carrier_protein]
|
2.3.1.184
acyl-homoserine-lactone synthase
|
–
|
|
|
BRENDA:
BS382761
|
|
|
|
dodecanoyl-[acyl-carrier_protein] + S-adenosyl-L-methionine <=> N-dodecanoyl-L-homoserine_lactone + [acyl-carrier_protein] + S-methyl-5''-thioadenosine
|
2.3.1.184
acyl-homoserine-lactone synthase
|
–
|
|
|
BRENDA:
BS435465
|
|
|
|
isovaleryl-ACP + S-adenosyl-L-methionine <=> [acyl-carrier_protein] + S-methyl-5''-thioadenosine + N-isovaleryl-L-homoserine_lactone
|
2.3.1.228
isovaleryl-homoserine lactone synthase
|
–
|
|
|
BRENDA:
BS435537
|
|
|
|
S-adenosyl-L-methionine + 3-oxodecanoyl-[acyl-carrier_protein] <=> 5''-methylthioadenosine + N-(3-oxodecanoyl)-L-homoserine_lactone + [acyl-carrier_protein]
|
2.3.1.184
acyl-homoserine-lactone synthase
|
–
|
|
|
BRENDA:
BS380745
|
|
|
|
S-adenosyl-L-methionine + decanoyl-[acyl-carrier_protein] <=> 5''-methylthioadenosine + N-decanoyl-L-homoserine_lactone + [acyl-carrier_protein]
|
2.3.1.184
acyl-homoserine-lactone synthase
|
–
|
|
|
BRENDA:
BS380750
|
|
|
|
N-decanoyl_-[acyl-carrier_protein] + S-adenosyl-L-methionine <=> [acyl-carrier_protein] + S-methyl-5''-thioadenosine + N-decanoyl-L-homoserine_lactone
|
2.3.1.184
acyl-homoserine-lactone synthase
|
–
|
|
|
BRENDA:
BS419479
|
|
|
|
3-hydroxydodecanoyl-[acyl-carrier_protein] + S-adenosyl-L-methionine <=> N-(3-hydroxydodecanoyl)-L-homoserine_lactone + [acyl-carrier_protein] + S-methyl-5''-thioadenosine
|
2.3.1.184
acyl-homoserine-lactone synthase
|
–
|
|
|
BRENDA:
BS435101
|
|
|
|
tetradecanoyl-[acyl-carrier_protein] + S-adenosyl-L-methionine <=> N-tetradecanoyl-L-homoserine_lactone + [acyl-carrier_protein] + S-methyl-5''-thioadenosine
|
2.3.1.184
acyl-homoserine-lactone synthase
|
–
|
|
|
BRENDA:
BS435871
|
|
|
|
S-adenosyl-L-methionine + 3-oxoundecanoyl-[acyl-carrier_protein] <=> 5''-methylthioadenosine + N-3-oxoundecanoyl-L-homoserine-1,4-lactone + [acyl-carrier_protein]
|
2.3.1.184
acyl-homoserine-lactone synthase
|
–
|
|
|
BRENDA:
BS382762
|
|
|
|
beta-Hydroxydecanoyl-[acyl-carrier_protein] + S-adenosyl-L-methionine <=> [acyl-carrier_protein] + S-methyl-5''-thioadenosine + N-(3-hydroxydecanoyl)-L-homoserine_lactone
|
2.3.1.184
acyl-homoserine-lactone synthase
|
–
|
|
|
BRENDA:
BS419471
|
|
|
|
N-butanoyl-[acyl-carrier_protein] + S-adenosyl-L-methionine <=> [acyl-carrier_protein] + S-methyl-5''-thioadenosine + N-butanoyl-L-homoserine_lactone
|
2.3.1.184
acyl-homoserine-lactone synthase
|
–
|
|
|
BRENDA:
BS419475
|
|
|
|
crotonyl-CoA + [acyl-carrier_protein] <=> CoA + a_2-butenoyl-[acyl_carrier_protein]
|
2.3.1.39
[acyl-carrier-protein] S-malonyltransferase
|
–
|
|
|
BRENDA:
BS454906
|
|
|
|
crotonyl-CoA + [acyl-carrier_protein] <=> CoA + a_crotonyl-[acyl-carrier_protein]
|
2.3.1.85
fatty-acid synthase system
|
–
|
|
|
BRENDA:
BS455484
|
|
|
|
butyryl-[acyl-carrier_protein] + H2O <=> Butyrate + [acyl-carrier_protein]
|
3.1.2.2
palmitoyl-CoA hydrolase
3.1.2.20
acyl-CoA hydrolase
|
–
–
|
|
|
BRENDA:
BS360770
|
|
|
|
oleoyl-[acyl-carrier_protein] + NADH + H+ <=> cis-9-octadecenal + [acyl-carrier_protein] + NAD+
|
1.2.1.80
long-chain acyl-[acyl-carrier-protein] reductase
|
–
|
|
|
BRENDA:
BS415077-a
|
|
|
|
palmitoyl-[acyl-carrier_protein] + NADH + H+ <=> octadecanal + [acyl-carrier_protein] + NAD+
|
1.2.1.80
long-chain acyl-[acyl-carrier-protein] reductase
|
–
|
|
|
BRENDA:
BS413382-a
|
|
|
|
acyl-CoA + [acyl-carrier_protein] <=> acyl-[acyl-carrier_protein] + CoA
|
2.3.1.41
beta-ketoacyl-[acyl-carrier-protein] synthase I
|
–
|
|
|
BRENDA:
BS320880
|
|
|
|
stearoyl-[acyl-carrier_protein] + 2-acyl-3-D-galactosyl-sn-glycerol <=> [acyl-carrier_protein] + 2-acyl-3-D-galactosyl-1-stearoyl-sn-glycerol
|
2.3.1.141
galactosylacylglycerol O-acyltransferase
|
–
|
|
|
BRENDA:
BS320512
|
|
|
|
oleoyl-[acyl-carrier_protein] + 1-oleoyl-sn-glycerol_3-phosphate <=> [acyl-carrier_protein] + dioleoyl_phosphatidic_acid
|
2.3.1.51
1-acylglycerol-3-phosphate O-acyltransferase
|
–
|
|
|
BRENDA:
BS321017
|
|
|
|
tetradecanoyl-[acyl-carrier_protein] + (3-deoxy-alpha-D-manno-oct-2-ulopyranosylonate)-(2->4)-(3-deoxy-alpha-D-manno-oct-2-ulopyranosylonate)-(2->6)-2-deoxy-2-[[(3R)-3-(dodecanoyloxy)tetradecanoyl]amino]-3-O-[(3R)-3-hydroxytetradecanoyl]-4-O-phosphono-beta-D-glucopyranosyl-(1->6)-2-deoxy-3-O-[(3R)-3-hydroxytetradecanoyl]-2-[[(3R)-3-hydroxytetradecanoyl]amino]-1-O-phosphono-alpha-D-glucopyranose <=> (3-deoxy-alpha-D-manno-oct-2-ulopyranosylonate)-(2->4)-(3-deoxy-alpha-D-manno-oct-2-ulopyranosylonate)-(2->6)-2-deoxy-2-[[(3R)-3-(dodecanoyloxy)tetradecanoyl]amino]-3-O-[(3R)-3-(tetradecanoyloxy)tetradecanoyl]-4-O-phospho-beta-D-glucopyranosyl-(1->6)-2-deoxy-3-O-[(3R)-3-hydroxytetradecanoyl]-2-[[(3R)-3-hydroxytetradecanoyl]amino]-1-O-phosphono-alpha-D-glucopyranose + [acyl-carrier_protein]
|
2.3.1.243
lauroyl-Kdo2-lipid IVA myristoyltransferase
|
–
|
|
|
BRENDA:
BR51110
|
|
|
|
palmitoleoyl-[acyl-carrier_protein] + (3-deoxy-alpha-D-manno-oct-2-ulopyranosylonate)-(2->4)-(3-deoxy-alpha-D-manno-oct-2-ulopyranosylonate)-(2->6)-2-deoxy-2-{[(3R)-3-hydroxytetraadecanoyl]amino}-3-O-[(3R)-3-hydroxytetradecanoyl]-4-O-phosphono-beta-D-glucopyranosyl-(1->6)-2-deoxy-3-O-[(3R)-3-hydroxytetradecanoyl]-2-{[(3R)-3-hydroxytetradecanoyl]amino}-1-O-phosphono-alpha-D-glucopyranose <=> (3-deoxy-alpha-D-manno-oct-2-ulopyranosylonate)-(2->4)-(3-deoxy-alpha-D-manno-oct-2-ulopyranosylonate)-(2->6)-2-deoxy-2-[[(3R)-3-((9Z)-hexadec-9-enoyloxy)tetradecanoyl]amino]-3-O-[(3R)-3-hydroxytetradecanoyl]-4-O-phosphono-beta-D-glucopyranosyl-(1->6)-2-deoxy-3-O-[(3R)-3-hydroxytetradecanoyl]-2-[[(3R)-3-hydroxytetradecanoyl]amino]-1-O-phosphono-alpha-D-glucopyranose + [acyl-carrier_protein]
|
2.3.1.242
Kdo2-lipid IVA palmitoleoyltransferase
|
–
|
|
|
BRENDA:
BR51109
|
|
|
|
dodecanoyl-[acyl-carrier_protein] + (3-deoxy-alpha-D-manno-oct-2-ulopyranosylonate)-(2->4)-(3-deoxy-alpha-D-manno-oct-2-ulopyranosylonate)-(2->6)-2-deoxy-2-{[(3R)-3-hydroxytetraadecanoyl]amino}-3-O-[(3R)-3-hydroxytetradecanoyl]-4-O-phosphono-beta-D-glucopyranosyl-(1->6)-2-deoxy-3-O-[(3R)-3-hydroxytetradecanoyl]-2-{[(3R)-3-hydroxytetradecanoyl]amino}-1-O-phosphono-alpha-D-glucopyranose <=> (3-deoxy-alpha-D-manno-oct-2-ulopyranosylonate)-(2->4)-(3-deoxy-alpha-D-manno-oct-2-ulopyranosylonate)-(2->6)-2-deoxy-2-[[(3R)-3-(dodecanoyloxy)tetradecanoyl]amino]-3-O-[(3R)-3-hydroxytetradecanoyl]-4-O-phosphono-beta-D-glucopyranosyl-(1->6)-2-deoxy-3-O-[(3R)-3-hydroxytetradecanoyl]-2-[[(3R)-3-hydroxytetradecanoyl]amino]-1-O-phosphono-alpha-D-glucopyranose + [acyl-carrier_protein]
|
2.3.1.241
Kdo2-lipid IVA lauroyltransferase
|
–
|
|
|
BRENDA:
BS428600
|
|
|
|
4-(gamma-L-glutamylamino)-(S)-2-hydroxylbutanoyl-[BtrI_acyl-carrier_protein] + neomycin <=> gamma-L-glutamyl-neomycin + [acyl-carrier_protein]
|
2.3.2.19
ribostamycin:4-(gamma-L-glutamylamino)-(S)-2-hydroxybutanoyl-[BtrI acyl-carrier protein] 4-(gamma-L-glutamylamino)-(S)-2-hydroxybutanoate transferase
|
–
|
|
|
BRENDA:
BS420020
|
|
|
|
4-(gamma-L-glutamylamino)-(S)-2-hydroxylbutanoyl-[BtrI_acyl-carrier_protein] + paromomycin <=> gamma-L-glutamyl-paromomycin + [acyl-carrier_protein]
|
2.3.2.19
ribostamycin:4-(gamma-L-glutamylamino)-(S)-2-hydroxybutanoyl-[BtrI acyl-carrier protein] 4-(gamma-L-glutamylamino)-(S)-2-hydroxybutanoate transferase
|
–
|
|
|
BRENDA:
BS420021
|
|
|
|
(R,S)-3-hydroxymyristoyl-[acyl-carrier_protein] + UDP-3-O-((3R)-3-hydroxymyristoyl)-alpha-D-glucosamine <=> UDP-2,3-bis((3R)-3-hydroxymyristoyl)-alpha-D-glucosamine + [acyl-carrier_protein]
|
2.3.1.191
UDP-3-O-(3-hydroxymyristoyl)glucosamine N-acyltransferase
|
–
|
|
|
BRENDA:
BS403116
|
|
|
|
(R,S)-3-hydroxypalmitoyl-[acyl-carrier_protein] + UDP-3-O-((3R)-3-hydroxymyristoyl)-alpha-D-glucosamine <=> UDP-2,3-bis((3R)-3-hydroxymyristoyl)-alpha-D-glucosamine + [acyl-carrier_protein]
|
2.3.1.191
UDP-3-O-(3-hydroxymyristoyl)glucosamine N-acyltransferase
|
–
|
|
|
BRENDA:
BS403117
|
|
|
|
a_dodecanoyl-[acyl-carrier_protein] + (3-deoxy-alpha-D-manno-oct-2-ulopyranosylonate)-(2->4)-(3-deoxy-alpha-D-manno-oct-2-ulopyranosylonate)-(2->6)-2-deoxy-2-[[(3R)-3-(dodecanoyloxy)tetradecanoyl]amino]-3-O-[(3R)-3-hydroxytetradecanoyl]-4-O-phosphono-beta-D-glucopyranosyl-(1->6)-2-deoxy-3-O-[(3R)-3-hydroxytetradecanoyl]-2-[[(3R)-3-hydroxytetradecanoyl]amino]-1-O-phosphono-alpha-D-glucopyranose <=> (3-deoxy-alpha-D-manno-oct-2-ulopyranosylonate)-(2->4)-(3-deoxy-alpha-D-manno-oct-2-ulopyranosylonate)-(2->6)-2-deoxy-2-[[(3R)-3-(dodecanoyloxy)tetradecanoyl]amino]-3-O-[(3R)-3-(dodecanoyloxy)tetradecanoyl]-4-O-phosphono-beta-D-glucopyranosyl-(1->6)-2-deoxy-3-O-[(3R)-3-hydroxytetradecanoyl]-2-[[(3R)-3-hydroxytetradecanoyl]amino]-1-O-phosphono-alpha-D-glucopyranose + [acyl-carrier_protein]
|
2.3.1.243
lauroyl-Kdo2-lipid IVA myristoyltransferase
|
–
|
|
|
BRENDA:
BS435192
|
|
|
|
palmitoyl-[acyl-carrier_protein] + phosphate <=> hexadecanoyl_phosphate + [acyl-carrier_protein]
|
2.3.1.274
phosphate acyltransferase
|
–
|
|
|
BRENDA:
BS454458
|
|
|
|
palmitoyl-[acyl-carrier_protein] + phosphate <=> octadecanoyl_phosphate + [acyl-carrier_protein]
|
2.3.1.274
phosphate acyltransferase
|
–
|
|
|
BRENDA:
BS445765
|
|
|
|
4-(gamma-L-glutamylamino)-(S)-2-hydroxylbutanoyl-[BtrI_acyl-carrier_protein] + ribostamycin <=> gamma-L-glutamyl-butirosin_B + [acyl-carrier_protein]
|
2.3.2.19
ribostamycin:4-(gamma-L-glutamylamino)-(S)-2-hydroxybutanoyl-[BtrI acyl-carrier protein] 4-(gamma-L-glutamylamino)-(S)-2-hydroxybutanoate transferase
|
–
|
|
|
BRENDA:
BR50177
|
|
|
|
(3R)-3-hydroxymyristoyl-[acyl-carrier_protein] + UDP-N-acetyl-D-glucosamine <=> [acyl-carrier_protein] + UDP-3-O-((3R)-3-hydroxymyristoyl)-alpha-D-glucosamine
|
2.3.1.129
acyl-[acyl-carrier-protein]---UDP-N-acetylglucosamine O-acyltransferase
|
–
|
|
|
BRENDA:
BS398237
|
|
|
|
ethylmalonyl-CoA + [acyl-carrier_protein] <=> CoA + a_methylmalonyl-[acyl-carrier_protein]
|
2.3.1.B32
|
–
|
|
|
BRENDA:
BS435492
|
|
|
|
2-hydroxybutanoyl-CoA + [acyl-carrier_protein] <=> CoA + a_2-hydroxybutyryl-[acyl_carrier_protein]
|
2.3.1.39
[acyl-carrier-protein] S-malonyltransferase
|
–
|
|
|
BRENDA:
BS454931
|
|
|
|
(R)-3-hydroxydodecanoyl-[acyl-carrier_protein] + UDP-2-acetamido-3-amino-2,3-dideoxy-alpha-D-glucopyranose <=> [acyl-carrier_protein] + UDP-3-N-((3R)-3-hydroxylauroyl)-2-acetamido-3-amino-2,3-dideoxy-alpha-D-glucopyranose
|
2.3.1.129
acyl-[acyl-carrier-protein]---UDP-N-acetylglucosamine O-acyltransferase
|
–
|
|
|
BRENDA:
BS407644
|
|
|
|
undecanoyl-[acyl-carrier_protein] + H2O <=> [acyl-carrier_protein] + Undecanoate
|
3.1.2.14
oleoyl-[acyl-carrier-protein] hydrolase
3.1.2.21
dodecanoyl-[acyl-carrier-protein] hydrolase
|
–
–
|
|
|
BRENDA:
BS452603
|
|
|
|
octanoyl-[acyl-carrier_protein] + glycine_cleavage_system_H <=> [glycine_cleavage_system_H]-N6-octanoyl-L-lysine + [acyl-carrier_protein]
|
2.3.1.181
lipoyl(octanoyl) transferase
|
–
|
|
|
BRENDA:
BS419348
|
|
|
|
octanoyl-[acyl-carrier_protein] + apo-H_protein <=> APO_H-protein_N6-(octanoyl)lysine + [acyl-carrier_protein]
|
2.3.1.181
lipoyl(octanoyl) transferase
|
–
|
|
|
BRENDA:
BS378719
|
|
|
|
octanoyl-[acyl-carrier_protein] + apo-E2_domain <=> apo_E2-domain_protein_N6-(octanoyl)lysine + [acyl-carrier_protein]
|
2.3.1.181
lipoyl(octanoyl) transferase
|
–
|
|
|
BRENDA:
BS380165
|
|
|
|
octanoyl-[acyl-carrier_protein] + apo-H_protein <=> apo-H_protein_N6-(octanoyl)lysine + [acyl-carrier_protein]
|
2.3.1.181
lipoyl(octanoyl) transferase
|
–
|
|
|
BRENDA:
BS380166
|
|
|
|
octanoyl-[acyl-carrier_protein] + apo-pyruvate_dehydogenase_protein <=> apo-pyruvate_dehydrogenase_protein_N6-(octanoyl)lysine + [acyl-carrier_protein]
|
2.3.1.181
lipoyl(octanoyl) transferase
|
–
|
|
|
BRENDA:
BS380167
|
|
|
|
isovaleryl-CoA + [acyl-carrier_protein] <=> CoA + an_isovaleryl-[acyl_carrier_protein]
|
2.3.1.39
[acyl-carrier-protein] S-malonyltransferase
|
–
|
|
|
BRENDA:
BS455800
|
|
|
|
octanoyl-[acyl-carrier_protein] + Lipoyl-protein <=> octanoylated_lipoyl_protein + [acyl-carrier_protein]
|
6.3.1.20
lipoate---protein ligase
|
–
|
|
|
BRENDA:
BS382440
|
|
|
|
methylmalonyl-CoA + [acyl-carrier_protein] <=> CoA + a_methalmalonyl-[acyl-carrier_protein]
|
2.3.1.39
[acyl-carrier-protein] S-malonyltransferase
|
–
|
|
|
BRENDA:
BS456003
|
|
|
|
(3R)-3-hydroxymyristoyl-[acyl-carrier_protein] + UDP-N-butyrylglucosamine <=> [acyl-carrier_protein] + UDP-3-O-(3-hydroxytetradecanoyl)-N-butyrylglucosamine
|
2.3.1.129
acyl-[acyl-carrier-protein]---UDP-N-acetylglucosamine O-acyltransferase
|
–
|
|
|
BRENDA:
BS320409
|
|
|
|
isobutyryl-CoA + [acyl-carrier_protein] <=> CoA + an_isobutyryl-[acyl_carrier_protein]
|
2.3.1.39
[acyl-carrier-protein] S-malonyltransferase
|
–
|
|
|
BRENDA:
BS455798
|
|
|
|
(3R)-3-hydroxymyristoyl-[acyl-carrier_protein] + UDP-N-acetyl-D-glucosamine <=> [acyl-carrier_protein] + UDP-3-O-[(3R)-3-hydroxytetradecanoyl]-N-acetyl-alpha-D-glucosamine
|
2.3.1.129
acyl-[acyl-carrier-protein]---UDP-N-acetylglucosamine O-acyltransferase
|
–
|
|
|
BRENDA:
BR43990
|
|
|
|
(R,S)-3-hydroxymyristoyl-[acyl-carrier_protein] + UDP-N-acetyl-D-glucosamine <=> [acyl-carrier_protein] + UDP-3-O-[(3R)-3-hydroxytetradecanoyl]-N-acetyl-alpha-D-glucosamine
|
2.3.1.129
acyl-[acyl-carrier-protein]---UDP-N-acetylglucosamine O-acyltransferase
|
–
|
|
|
BRENDA:
BS320406
|
|
|
|
(S)-3-hydroxytetradecanoyl-[acyl-carrier_protein] + UDP-N-acetyl-D-glucosamine <=> [acyl-carrier_protein] + UDP-3-O-[(3R)-3-hydroxytetradecanoyl]-N-acetyl-alpha-D-glucosamine
|
2.3.1.129
acyl-[acyl-carrier-protein]---UDP-N-acetylglucosamine O-acyltransferase
|
–
|
|
|
BRENDA:
BS320407
|
|
|
|
octanoyl-[acyl-carrier_protein] + alpha-ketoglutarate_dehydrogenase_apo-E2_domain <=> alpha-ketoglutarate_dehydrogenase_E2-domain_N6-(octanoyl)lysine + [acyl-carrier_protein]
|
2.3.1.181
lipoyl(octanoyl) transferase
|
–
|
|
|
BRENDA:
BS435678
|
|
|
|
octanoyl-[acyl-carrier_protein] + glycine_dehydrogenase_H-protein <=> glycine_dehydrogenase_H-protein_N6-(octanoyl)lysine + [acyl-carrier_protein]
|
2.3.1.181
lipoyl(octanoyl) transferase
|
–
|
|
|
BRENDA:
BS435679
|
|
|
|
octanoyl-[acyl-carrier_protein] + pyruvate_dehydrogenase_apo-E2_domain <=> pyruvate_dehydrogenase_apo_E2-domain_N6-(octanoyl)lysine + [acyl-carrier_protein]
|
2.3.1.181
lipoyl(octanoyl) transferase
|
–
|
|
|
BRENDA:
BS435680
|
|
|
|
octanoyl-[acyl-carrier_protein] + [glycine_cleavage_system_3]-L-lysine <=> [glycine_cleavage_system_3]-N6-octanoyl-L-lysine + [acyl-carrier_protein]
|
2.3.1.181
lipoyl(octanoyl) transferase
|
–
|
|
|
BRENDA:
BS435682
|
|
|
|
decanoyl-[acyl-carrier_protein] + UDP-N-acetyl-D-glucosamine <=> [acyl-carrier_protein] + UDP-3-O-decanoyl-N-acetylglucosamine
|
2.3.1.129
acyl-[acyl-carrier-protein]---UDP-N-acetylglucosamine O-acyltransferase
|
–
|
|
|
BRENDA:
BS320413
|
|
|
|
vaccenoyl-[acyl_carrier_protein] + sn-glycerol_3-phosphate <=> [acyl-carrier_protein] + 1-vaccenoylglycerol_3-phosphate
|
2.3.1.15
glycerol-3-phosphate 1-O-acyltransferase
|
–
|
|
|
BRENDA:
BS451936
|
|
|
|
(R)-3-hydroxydodecanoyl-[acyl-carrier_protein] + UDP-N-acetyl-D-glucosamine <=> [acyl-carrier_protein] + UDP-3-O-(3-hydroxydodecanoyl)-N-acetyl-alpha-D-glucosamine
|
2.3.1.129
acyl-[acyl-carrier-protein]---UDP-N-acetylglucosamine O-acyltransferase
|
–
|
|
|
BRENDA:
BS375460
|
|
|
|
(R,S)-3-hydroxydodecanoyl-[acyl-carrier_protein] + UDP-N-acetyl-D-glucosamine <=> [acyl-carrier_protein] + UDP-3-O-(3-hydroxydodecanoyl)-N-acetyl-alpha-D-glucosamine
|
2.3.1.129
acyl-[acyl-carrier-protein]---UDP-N-acetylglucosamine O-acyltransferase
|
–
|
|
|
BRENDA:
BS320410
|
|
|
|
(3R)-3-hydroxypalmitoyl-[acyl-carrier_protein] + UDP-N-acetyl-D-glucosamine <=> [acyl-carrier_protein] + UDP-3-O-(3-hydroxyhexadecanoyl)-N-acetyl-alpha-D-glucosamine
|
2.3.1.129
acyl-[acyl-carrier-protein]---UDP-N-acetylglucosamine O-acyltransferase
|
–
|
|
|
BRENDA:
BS375461
|
|
|
|
(R,S)-3-hydroxyhexadecanoyl-[acyl-carrier_protein] + UDP-N-acetyl-D-glucosamine <=> [acyl-carrier_protein] + UDP-3-O-(3-hydroxyhexadecanoyl)-N-acetyl-alpha-D-glucosamine
|
2.3.1.129
acyl-[acyl-carrier-protein]---UDP-N-acetylglucosamine O-acyltransferase
|
–
|
|
|
BRENDA:
BS320414
|
|
|
|
(R,S)-3-hydroxydodecanoyl-[acyl-carrier_protein] + UDP-N-acetyl-D-glucosamine <=> [acyl-carrier_protein] + UDP-3-O-(3-hydroxylauroyl)-N-acetyl-alpha-D-glucosamine
|
2.3.1.129
acyl-[acyl-carrier-protein]---UDP-N-acetylglucosamine O-acyltransferase
|
–
|
|
|
BRENDA:
BS320412
|
|
|
|
(3R)-3-hydroxymyristoyl-[acyl-carrier_protein] + UDP-N-acetyl-D-glucosamine <=> [acyl-carrier_protein] + UDP-3-O-(3-hydroxymyristoyl)-N-acetyl-alpha-D-glucosamine
|
2.3.1.129
acyl-[acyl-carrier-protein]---UDP-N-acetylglucosamine O-acyltransferase
|
–
|
|
|
BRENDA:
BS398238
|
|
|
|
(R,S)-3-hydroxymyristoyl-[acyl-carrier_protein] + UDP-N-acetyl-D-glucosamine <=> [acyl-carrier_protein] + UDP-3-O-(3-hydroxymyristoyl)-N-acetyl-alpha-D-glucosamine
|
2.3.1.129
acyl-[acyl-carrier-protein]---UDP-N-acetylglucosamine O-acyltransferase
|
–
|
|
|
BRENDA:
BS320411
|
|
|
|
(3R)-3-hydroxymyristoyl-[acyl-carrier_protein] + UDP-N-propionyl-alpha-D-glucosamine <=> [acyl-carrier_protein] + UDP-3-O-(3-hydroxytetradecanoyl)-N-propionyl-alpha-D-glucosamine
|
2.3.1.129
acyl-[acyl-carrier-protein]---UDP-N-acetylglucosamine O-acyltransferase
|
–
|
|
|
BRENDA:
BS320408
|
|
|
|
tetradecanoyl-[acyl-carrier_protein] + UDP-N-acetyl-D-glucosamine <=> [acyl-carrier_protein] + UDP-3-O-myristoyl-N-acetyl-alpha-D-glucosamine
|
2.3.1.129
acyl-[acyl-carrier-protein]---UDP-N-acetylglucosamine O-acyltransferase
|
–
|
|
|
BRENDA:
BS320415
|
|
|
|
hydroxybutanoyl-CoA + [acyl-carrier_protein] <=> CoA + a_hydroxybutanoyl-[acyl-carrier_protein]
|
2.3.1.85
fatty-acid synthase system
|
–
|
|
|
BRENDA:
BS455777
|
|
|
|
methylbutanoyl-CoA + [acyl-carrier_protein] <=> CoA + a_methylbutanoyl-[acyl-carrier_protein]
|
2.3.1.85
fatty-acid synthase system
|
–
|
|
|
BRENDA:
BS456001
|
|
|
|
dodecanoyl-[acyl-carrier_protein] + dodecanoyl-Kdo2-lipid_IVA <=> dodecanoyl-(dodecanoyl)-Kdo2-lipid_IVA + [acyl-carrier_protein]
|
2.3.1.243
lauroyl-Kdo2-lipid IVA myristoyltransferase
|
–
|
|
|
BRENDA:
BS455600
|
|
|
|
palmitoyl-[acyl-carrier_protein] + dodecanoyl-Kdo2-lipid_IVA <=> dodecanoyl-(hexadecanoyl)-Kdo2-lipid_IVA + [acyl-carrier_protein]
|
2.3.1.243
lauroyl-Kdo2-lipid IVA myristoyltransferase
|
–
|
|
|
BRENDA:
BS455763
|
|
|
|
octanoyl-[acyl-carrier_protein] + dodecanoyl-Kdo2-lipid_IVA <=> dodecanoyl-(octanoyl)-Kdo2-lipid_IVA + [acyl-carrier_protein]
|
2.3.1.243
lauroyl-Kdo2-lipid IVA myristoyltransferase
|
–
|
|
|
BRENDA:
BS456122
|
|
|
|
octanoyl-[acyl-carrier_protein] + GCSH_protein <=> GCSH_protein_N6-(octanoyl)lysine + [acyl-carrier_protein]
|
2.3.1.181
lipoyl(octanoyl) transferase
|
–
|
|
|
BRENDA:
BS455307
|
|
|
|
tetradecanoyl-[acyl-carrier_protein] + alpha-Kdo-(2->4)-alpha-Kdo-(2->6)-lipid_IVA <=> tetradecanoyl-Kdo2-lipid_IVA + [acyl-carrier_protein]
|
2.3.1.241
Kdo2-lipid IVA lauroyltransferase
|
–
|
|
|
BRENDA:
BS455141
|
|
|
|
(R)-3-hydroxydodecanoyl-[acyl-carrier_protein] + UDP-N-acetyl-alpha-D-galalctosamine <=> [acyl-carrier_protein] + UDP-3-O-(3-hydroxydodecanoyl)-N-acetyl-alpha-D-galactosamine
|
2.3.1.129
acyl-[acyl-carrier-protein]---UDP-N-acetylglucosamine O-acyltransferase
|
–
|
|
|
BRENDA:
BS454755
|
|
|
|
R,S-3-hydroxypalmitoyl-ACP + UDP-N-acetyl-D-glucosamine <=> [acyl-carrier_protein] + UDP-3-O-(3-hydroxypalmioyl)-N-acetyl-alpha-D-glucosamine
|
2.3.1.129
acyl-[acyl-carrier-protein]---UDP-N-acetylglucosamine O-acyltransferase
|
–
|
|
|
BRENDA:
BS456311
|
|
|
|
(R)-3-hydroxydodecanoyl-[acyl-carrier_protein] + UDP-2-acetamido-3-amino-2,3-dideoxy-alpha-D-glucopyranose <=> [acyl-carrier_protein] + UDP-3-N-(3-hydroxydodecanoyl)-2-acetamido-3-amino-2,3-dideoxy-alpha-D-glucopyranose
|
2.3.1.129
acyl-[acyl-carrier-protein]---UDP-N-acetylglucosamine O-acyltransferase
|
–
|
|
|
BRENDA:
BS374961
|
|
|
|
(3R)-3-hydroxymyristoyl-[acyl-carrier_protein] + UDP-2-acetamido-3-amino-2,3-dideoxy-alpha-D-glucopyranose <=> [acyl-carrier_protein] + UDP-3-N-(3-hydroxytetradecanoyl)-2-acetamido-3-amino-2,3-dideoxy-alpha-D-glucopyranose
|
2.3.1.129
acyl-[acyl-carrier-protein]---UDP-N-acetylglucosamine O-acyltransferase
|
–
|
|
|
BRENDA:
BS374962
|
|
|
|
(3R)-3-hydroxydecanoyl-[acyl-carrier_protein] + UDP-2-acetamido-3-amino-2,3-dideoxy-alpha-D-glucopyranose <=> [acyl-carrier_protein] + UDP-3-N-(3-hydroxydecanoyl)-2-acetamido-3-amino-2,3-dideoxy-alpha-D-glucopyranose
|
2.3.1.129
acyl-[acyl-carrier-protein]---UDP-N-acetylglucosamine O-acyltransferase
|
–
|
|
|
BRENDA:
BS375459
|
|
|
|
phenylacetyl-CoA + [acyl-carrier_protein] <=> CoA + a_phenylacetyl-[acyl-carrier_protein]
|
2.3.1.85
fatty-acid synthase system
|
–
|
|
|
BRENDA:
BS456257
|
|
|
|
(3R)-3-hydroxyarachidonoyl-[acyl-carrier_protein] + UDP-3-O-((3R)-3-hydroxymyristoyl)-alpha-D-glucosamine <=> UDP-2-N-((3R)-3-hydroxyarachidonoyl)-3-O-((3R)-3-hydroxymyristoyl)-alpha-D-glucosamine + [acyl-carrier_protein]
|
2.3.1.191
UDP-3-O-(3-hydroxymyristoyl)glucosamine N-acyltransferase
|
–
|
|
|
BRENDA:
BS402282
|
|
|
|
stearoyl-[acyl-carrier_protein] + NADPH <=> hexadecanol + [acyl-carrier_protein] + NADP+
|
1.2.1.50
long-chain acyl-protein thioester reductase
|
–
|
|
|
BRENDA:
BS389498
|
|
|
|
oleoyl-[acyl-carrier_protein] + NADPH + H+ <=> cis-9-octadecenal + [acyl-carrier_protein] + NADP+
|
1.2.1.80
long-chain acyl-[acyl-carrier-protein] reductase
|
–
|
|
|
BRENDA:
BS415077
|
|
|
|
palmitoyl-[acyl-carrier_protein] + NADPH + H+ <=> octadecanal + [acyl-carrier_protein] + NADP+
|
1.2.1.80
long-chain acyl-[acyl-carrier-protein] reductase
|
–
|
|
|
BRENDA:
BS413382
|
|
|
|
cis-3-decenoyl-[acyl-carrier_protein] + malonyl-[acyl-carrier_protein] <=> 3-oxo-cis-5-dodecenoyl-[acyl-carrier_protein] + [acyl-carrier_protein]
|
2.3.1.41
beta-ketoacyl-[acyl-carrier-protein] synthase I
|
–
|
|
|
BRENDA:
BS407181
|
|
|
|
eicosanoyl-[acyl-carrier_protein] + malonyl-[acyl-carrier_protein] <=> 3-oxodocosanoyl-[acyl-carrier_protein] + CO2 + [acyl-carrier_protein]
|
2.3.1.41
beta-ketoacyl-[acyl-carrier-protein] synthase I
|
–
|
|
|
BRENDA:
BS320884
|
|
|
|
palmitoyl-[acyl-carrier_protein] + malonyl-[acyl-carrier_protein] <=> 3-oxooctanoyl-[acyl-carrier_protein] + CO2 + [acyl-carrier_protein]
|
2.3.1.41
beta-ketoacyl-[acyl-carrier-protein] synthase I
|
–
|
|
|
BRENDA:
BS377478
|
|
|
|
palmitoyl-[acyl-carrier_protein] + malonyl-[acyl-carrier_protein] <=> 3-oxoeicosanoyl-[acyl-carrier_protein] + CO2 + [acyl-carrier_protein]
|
2.3.1.41
beta-ketoacyl-[acyl-carrier-protein] synthase I
|
–
|
|
|
BRENDA:
BS320876
|
|
|
|
a_(Z)-hexadec-11-enoyl-[acyl-carrier_protein] + malonyl-[acyl-carrier_protein] <=> a_(Z)-3-oxooctadeca-13-enoyl-[acyl-carrier_protein] + CO2 + [acyl-carrier_protein]
|
2.3.1.179
beta-ketoacyl-[acyl-carrier-protein] synthase II
|
–
|
|
|
BRENDA:
BR51682
|
|
|
|
acyl-[acyl-carrier_protein] + malonyl-[acyl-carrier_protein] <=> acyl-[acyl-carrier_protein] + CO2 + [acyl-carrier_protein]
|
2.3.1.41
beta-ketoacyl-[acyl-carrier-protein] synthase I
|
–
|
|
|
BRENDA:
BS386213
|
|
|
|
Malonyl_pantetheine + [acyl-carrier_protein] <=> pantetheine + malonyl-[acyl-carrier_protein]
|
2.3.1.39
[acyl-carrier-protein] S-malonyltransferase
|
–
|
|
|
BRENDA:
BS320854
|
|
|
|
octanoyl-[acyl-carrier_protein] + malonyl-[acyl-carrier_protein] <=> decanoyl-[acyl-carrier_protein] + CO2 + [acyl-carrier_protein]
|
2.3.1.41
beta-ketoacyl-[acyl-carrier-protein] synthase I
|
–
|
|
|
BRENDA:
BS388285
|
|
|
|
decanoyl-[acyl-carrier_protein] + malonyl-[acyl-carrier_protein] <=> dodecanoyl-[acyl-carrier_protein] + CO2 + [acyl-carrier_protein]
|
2.3.1.41
beta-ketoacyl-[acyl-carrier-protein] synthase I
|
–
|
|
|
BRENDA:
BS320871
|
|
|
|
propionyl-[acyl-carrier_protein] + malonyl-[acyl-carrier_protein] <=> beta-ketopentanoyl-[acyl-carrier_protein] + CO2 + [acyl-carrier_protein]
|
2.3.1.41
beta-ketoacyl-[acyl-carrier-protein] synthase I
|
–
|
|
|
BRENDA:
BS320866
|
|
|
|
tetradecanoyl-[acyl-carrier_protein] + malonyl-[acyl-carrier_protein] <=> stearoyl-[acyl-carrier_protein] + CO2 + [acyl-carrier_protein]
|
2.3.1.41
beta-ketoacyl-[acyl-carrier-protein] synthase I
|
–
|
|
|
BRENDA:
BS388281
|
|
|
|
(Z)-hexadec-11-enoyl-[acyl-carrier_protein] + malonyl-[acyl-carrier_protein] <=> (Z)-3-oxooctadec-13-enoyl-[acyl-carrier_protein] + CO2 + [acyl-carrier_protein]
|
2.3.1.179
beta-ketoacyl-[acyl-carrier-protein] synthase II
2.3.1.294
meromycolic acid 3-oxoacyl-(acyl carrier protein) synthase II
|
–
–
|
|
|
BRENDA:
BR48669
|
|
|
|
acetyl-[acyl-carrier_protein] + malonyl-[acyl-carrier_protein] <=> acetoacyl-[acyl-carrier_protein] + CO2 + [acyl-carrier_protein]
|
2.3.1.41
beta-ketoacyl-[acyl-carrier-protein] synthase I
|
–
|
|
|
BRENDA:
BS320864
|
|
|
|
malonyl-[acyl-carrier_protein] + 2-aminobenzoyl-CoA <=> CoA + [acyl-carrier_protein] + 4-hydroxyquinolin-2(1H)-one + CO2
|
2.3.1.230
2-heptyl-4(1H)-quinolone synthase
|
–
|
|
|
BRENDA:
BS423816
|
|
|
|
dodecanoyl-[acyl-carrier_protein] + malonyl-[acyl-carrier_protein] <=> tetradecanoyl-[acyl-carrier_protein] + CO2 + [acyl-carrier_protein]
|
2.3.1.41
beta-ketoacyl-[acyl-carrier-protein] synthase I
|
–
|
|
|
BRENDA:
BS388280
|
|
|
|
hexanoyl-[acyl-carrier_protein] + malonyl-[acyl-carrier_protein] <=> octanoyl-[acyl-carrier_protein] + CO2 + [acyl-carrier_protein]
|
2.3.1.41
beta-ketoacyl-[acyl-carrier-protein] synthase I
|
–
|
|
|
BRENDA:
BS388284
|
|
|
|
butyryl-[acyl-carrier_protein] + malonyl-[acyl-carrier_protein] <=> hexanoyl-[acyl-carrier_protein] + CO2 + [acyl-carrier_protein]
|
2.3.1.41
beta-ketoacyl-[acyl-carrier-protein] synthase I
|
–
|
|
|
BRENDA:
BS388283
|
|
|
|
4-hexadecenoyl-[acyl-carrier_protein] + malonyl-[acyl-carrier_protein] <=> 3-oxo-6-octadecenoyl-[acyl-carrier_protein] + CO2 + [acyl-carrier_protein]
|
2.3.1.41
beta-ketoacyl-[acyl-carrier-protein] synthase I
|
–
|
|
|
BRENDA:
BS320879
|
|
|
|
cis-mono-unsaturated_acyl-[acyl-carrier_protein] + malonyl-[acyl-carrier_protein] <=> cis-mono-unsaturated_3-oxoacyl-[acyl-carrier_protein] + CO2 + [acyl-carrier_protein]
|
2.3.1.41
beta-ketoacyl-[acyl-carrier-protein] synthase I
|
–
|
|
|
BRENDA:
BS320863
|
|
|
|
saturated_acyl-[acyl-carrier_protein] + malonyl-[acyl-carrier_protein] <=> 3-oxoacyl-[acyl-carrier_protein] + CO2 + [acyl-carrier_protein]
|
2.3.1.41
beta-ketoacyl-[acyl-carrier-protein] synthase I
|
–
|
|
|
BRENDA:
BS320862
|
|
|
|
an_ultra-long-chain_di-unsaturated_acyl-[acyl-carrier_protein] + malonyl-[acyl-carrier_protein] <=> an_ultra-long-chain_di-unsaturated_3-oxo-fatty_acyl-[acyl-carrier_protein] + CO2 + [acyl-carrier_protein]
|
2.3.1.294
meromycolic acid 3-oxoacyl-(acyl carrier protein) synthase II
|
–
|
|
|
BRENDA:
BR52916
|
|
|
|
an_ultra-long-chain_mono-unsaturated_acyl-[acyl-carrier_protein] + malonyl-[acyl-carrier_protein] <=> an_ultra-long-chain_mono-unsaturated_3-oxo-fatty_acyl-[acyl-carrier_protein] + CO2 + [acyl-carrier_protein]
|
2.3.1.293
meromycolic acid 3-oxoacyl-(acyl carrier protein) synthase I
|
–
|
|
|
BRENDA:
BR52915
|
|
|
|
linoleoyl-[acyl-carrier_protein] + H2O <=> [acyl-carrier_protein] + linoleic_acid
|
3.1.2.14
oleoyl-[acyl-carrier-protein] hydrolase
|
–
|
|
|
BRENDA:
BS447693
|
|
|
|
[acyl-carrier_protein] + ATP <=> AMP-ACP + diphosphate
|
2.7.7.61
citrate lyase holo-[acyl-carrier protein] synthase
|
–
|
|
|
BRENDA:
BS323486
|
|
|
|
malonyl-CoA + [acyl-carrier_protein] <=> CoA + a_methylmalonyl-[acyl-carrier_protein]
|
2.3.1.B32
|
–
|
|
|
BRENDA:
BS435601
|
|
|
|
caproyl-[acyl-carrier_protein] + H2O <=> [acyl-carrier_protein] + hexanoate
|
3.1.2.14
oleoyl-[acyl-carrier-protein] hydrolase
|
–
|
|
|
BRENDA:
BS447260
|
|
|
|
capryloyl-[acyl-carrier_protein] + H2O <=> [acyl-carrier_protein] + Octanoate
|
3.1.2.14
oleoyl-[acyl-carrier-protein] hydrolase
|
–
|
|
|
BRENDA:
BS447261
|
|
|
|
linolenoyl-[acyl-carrier_protein] + H2O <=> [acyl-carrier_protein] + linolenic_acid
|
3.1.2.14
oleoyl-[acyl-carrier-protein] hydrolase
|
–
|
|
|
BRENDA:
BS447691
|
|
|
|
nonanoyl-[acyl-carrier_protein] + H2O <=> [acyl-carrier_protein] + Nonanoate
|
3.1.2.14
oleoyl-[acyl-carrier-protein] hydrolase
|
–
|
|
|
BRENDA:
BS447918
|
|
|
|
ATP + L-glutamate + [acyl-carrier_protein] <=> ADP + phosphate + L-glutamyl-[BtrI_acyl-carrier_protein]
|
6.2.1.39
[butirosin acyl-carrier protein]---L-glutamate ligase
|
–
|
|
|
BRENDA:
BR50212
|
|
|
|
ATP + 4-aminobutanoate + [acyl-carrier_protein] <=> ADP + phosphate + 4-aminobutanoyl-S-[BtrI_acyl-carrier_protein]
|
6.2.1.39
[butirosin acyl-carrier protein]---L-glutamate ligase
|
–
|
|
|
BRENDA:
BS420309
|
|
|
|
dodecenoyl-[Staphylococcus_aureus_acyl_carrier_protein] + H2O <=> 2-trans-Dodecenoic_acid + [acyl-carrier_protein]
|
3.1.2.14
oleoyl-[acyl-carrier-protein] hydrolase
|
–
|
|
|
BRENDA:
BS64583
|
|
|
|
palmitoyl-[acyl-carrier_protein] + lysophosphatidic_acid <=> [acyl-carrier_protein] + 1-acyl-2-palmitoyl-sn-glycerol_3-phosphate
|
2.3.1.51
1-acylglycerol-3-phosphate O-acyltransferase
|
–
|
|
|
BRENDA:
BS456241
|
|
|
|
tetradecanoyl-[acyl-carrier_protein] + lysophosphatidic_acid <=> [acyl-carrier_protein] + 1-acyl-2-myristoyl-sn-glycerol_3-phosphate
|
2.3.1.51
1-acylglycerol-3-phosphate O-acyltransferase
|
–
|
|
|
BRENDA:
BS456053
|
|
|
|
stearoyl-[acyl-carrier_protein] + lysophosphatidic_acid <=> [acyl-carrier_protein] + 1-acyl-2-palmitoyl-sn-glycerol_3-phosphate
|
2.3.1.51
1-acylglycerol-3-phosphate O-acyltransferase
|
–
|
|
|
BRENDA:
BS321029
|
|
|
|
myristoleoyl-[acyl-carrier_protein] + H2O <=> myristoleic_acid + [acyl-carrier_protein]
|
3.1.2.14
oleoyl-[acyl-carrier-protein] hydrolase
|
–
|
|
|
BRENDA:
BS364434
|
|
|
|
ATP + hex-5-ynoic_acid + [acyl-carrier_protein] <=> AMP + diphosphate + hex-5-ynoyl-[acyl-carrier_protein]
|
6.2.1.47
medium-chain-fatty-acid---[acyl-carrier-protein] ligase
|
–
|
|
|
BRENDA:
BS437131
|
|
|
|
ATP + hex-5-enoic_acid + [acyl-carrier_protein] <=> AMP + diphosphate + hex-5-enoyl-[acyl-carrier_protein]
|
6.2.1.47
medium-chain-fatty-acid---[acyl-carrier-protein] ligase
|
–
|
|
|
BRENDA:
BS437130
|
|
|
|
ATP + Decanoate + [acyl-carrier_protein] <=> AMP + diphosphate + long-chain_decanoyl-[acyl-carrier_protein]
|
6.2.1.20
long-chain-fatty-acid---[acyl-carrier-protein] ligase
|
–
|
|
|
BRENDA:
BS443132
|
|
|
|
ATP + oleic_acid + [acyl-carrier_protein] <=> AMP + diphosphate + oleoyl-[acyl-carrier_protein]
|
6.2.1.20
long-chain-fatty-acid---[acyl-carrier-protein] ligase
|
–
|
|
|
BRENDA:
BS212
|
|
|
|
ATP + cis-vaccenic_acid + [acyl-carrier_protein] <=> AMP + diphosphate + cis-vaccenoyl-[acyl-carrier_protein]
|
6.2.1.20
long-chain-fatty-acid---[acyl-carrier-protein] ligase
|
–
|
|
|
BRENDA:
BS218
|
|
|
|
ATP + palmitoleic_acid + [acyl-carrier_protein] <=> AMP + diphosphate + palmitoleoyl-[acyl-carrier_protein]
|
6.2.1.20
long-chain-fatty-acid---[acyl-carrier-protein] ligase
|
–
|
|
|
BRENDA:
BS221
|
|
|
|
ATP + D-alanine + [acyl-carrier_protein] <=> D-alanyl_carrier_protein + AMP + diphosphate
|
6.2.1.54
D-alanine---[D-alanyl-carrier protein] ligase
|
–
|
|
|
BRENDA:
BS141675
|
|
|
|
ATP + linoleic_acid + [acyl-carrier_protein] <=> AMP + diphosphate + linoleoyl-[acyl-carrier_protein]
|
6.2.1.20
long-chain-fatty-acid---[acyl-carrier-protein] ligase
|
–
|
|
|
BRENDA:
BS219
|
|
|
|
ATP + L-alanine + [acyl-carrier_protein] <=> AMP + diphosphate + an_L-alanyl-[acyl-carrier_protein]
|
6.2.1.B5
|
–
|
|
|
BRENDA:
BR49267
|
|
|
|
octanoyl-[acyl-carrier_protein] + protein <=> protein_N6-(octanoyl)lysine + [acyl-carrier_protein]
|
2.3.1.181
lipoyl(octanoyl) transferase
|
–
|
B
|
|
BRENDA:
BR48667
|
|
|
|
[acyl-carrier_protein] + H2O <=> 4''-phosphopantetheine + protein
|
3.1.4.14
[acyl-carrier-protein] phosphodiesterase
|
–
|
|
|
BRENDA:
BS369738
|
|
|
|
propionyl-[acyl-carrier_protein] + L-alanine <=> 1-[(4S)-4-amino-5-oxoheptyl]guanidine + CO2 + [acyl-carrier_protein]
|
2.3.1.47
8-amino-7-oxononanoate synthase
|
–
|
|
|
BRENDA:
BS456304
|
|
|
|
a_dodecanoyl-[acyl-carrier_protein] + (3-deoxy-alpha-D-manno-oct-2-ulopyranosylonate)-(2->4)-(3-deoxy-alpha-D-manno-oct-2-ulopyranosylonate)-(2->6)-2-deoxy-2-{[(3R)-3-hydroxytetraadecanoyl]amino}-3-O-[(3R)-3-hydroxytetradecanoyl]-4-O-phosphono-beta-D-glucopyranosyl-(1->6)-2-deoxy-3-O-[(3R)-3-hydroxytetradecanoyl]-2-{[(3R)-3-hydroxytetradecanoyl]amino}-1-O-phosphono-alpha-D-glucopyranose <=> (3-deoxy-alpha-D-manno-oct-2-ulopyranosylonate)-(2->4)-(3-deoxy-alpha-D-manno-oct-2-ulopyranosylonate)-(2->6)-2-deoxy-2-[[(3R)-3-(dodecanoyloxy)tetradecanoyl]amino]-3-O-[(3R)-3-hydroxytetradecanoyl]-4-O-phosphono-beta-D-glucopyranosyl-(1->6)-2-deoxy-3-O-[(3R)-3-hydroxytetradecanoyl]-2-[[(3R)-3-hydroxytetradecanoyl]amino]-1-O-phosphono-alpha-D-glucopyranose + [acyl-carrier_protein]
|
2.3.1.241
Kdo2-lipid IVA lauroyltransferase
|
–
|
|
|
BRENDA:
BR51108
|
|
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tetradecanoyl-[acyl-carrier_protein] + (3-deoxy-alpha-D-manno-oct-2-ulopyranosylonate)-(2->4)-(3-deoxy-alpha-D-manno-oct-2-ulopyranosylonate)-(2->6)-2-deoxy-2-{[(3R)-3-hydroxytetraadecanoyl]amino}-3-O-[(3R)-3-hydroxytetradecanoyl]-4-O-phosphono-beta-D-glucopyranosyl-(1->6)-2-deoxy-3-O-[(3R)-3-hydroxytetradecanoyl]-2-{[(3R)-3-hydroxytetradecanoyl]amino}-1-O-phosphono-alpha-D-glucopyranose <=> (3-deoxy-alpha-D-manno-oct-2-ulopyranosylonate)-(2->4)-(3-deoxy-alpha-D-manno-oct-2-ulopyranosylonate)-(2->6)-2-deoxy-2-[[(3R)-3-(myristoyloxy)tetradecanoyl]amino]-3-O-[(3R)-3-hydroxytetradecanoyl]-4-O-phosphono-beta-D-glucopyranosyl-(1->6)-2-deoxy-3-O-[(3R)-3-hydroxytetradecanoyl]-2-[[(3R)-3-hydroxytetradecanoyl]amino]-1-O-phosphono-alpha-D-glucopyranose + [acyl-carrier_protein]
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2.3.1.242
Kdo2-lipid IVA palmitoleoyltransferase
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–
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BRENDA:
BS435193
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